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  • Energy Research
  • 2021-2025
  • 13. Climate action
  • 7. Clean energy
  • 12. Responsible consumption
  • Aurora Universities Network

  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Marroccoli M.; Ibris N.; Telesca A.; Tregambi C.; +5 Authors

    Dolomite-based binders are characterised by interesting technical and environmental features. For their synthesis, sources of both CaO and MgO are required. The idea developed in this work is to couple the synthesis of dolomite-based binders, starting from a natural dolomite, through the concept of concentrated solar energy (needed to drive the endothermal dolomite calcination process) in fluidised bed reactors. To this end, a fluidised bed system, where the concentrated solar radiation is mimicked by the use of Xe-lamps (short-arc), has been set up and operated. Natural dolomite (sieved in the 420-590 ?m size range) was calcined at a nominal temperature of 850 °C, and bed temperature profiles during solar-driven calcination were investigated. Then, four binders were prepared by mixing slaked dolomite (obtained from the hydration of solar calcined dolomite) with either blast furnace slag or coal fly ash as supplementary cementitious materials. The binders were hydrated for curing times ranging from 7 to 56 days. X-ray fluorescence, X-ray diffraction and combined differential thermal and thermogravimetric analyses were employed as characterisation techniques both to analyse the chemical composition of starting materials and to investigate the evolution of the hydration in the four systems.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao IRIS Cnrarrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    CNR ExploRA
    Article . 2022
    Data sources: CNR ExploRA
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Solar Energy
    Article . 2022 . Peer-reviewed
    License: Elsevier TDM
    Data sources: Crossref
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao IRIS Cnrarrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      CNR ExploRA
      Article . 2022
      Data sources: CNR ExploRA
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Solar Energy
      Article . 2022 . Peer-reviewed
      License: Elsevier TDM
      Data sources: Crossref
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      addClaim

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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Marroccoli M.; Ibris N.; Telesca A.; Tregambi C.; +5 Authors

    Dolomite-based binders are characterised by interesting technical and environmental features. For their synthesis, sources of both CaO and MgO are required. The idea developed in this work is to couple the synthesis of dolomite-based binders, starting from a natural dolomite, through the concept of concentrated solar energy (needed to drive the endothermal dolomite calcination process) in fluidised bed reactors. To this end, a fluidised bed system, where the concentrated solar radiation is mimicked by the use of Xe-lamps (short-arc), has been set up and operated. Natural dolomite (sieved in the 420-590 ?m size range) was calcined at a nominal temperature of 850 °C, and bed temperature profiles during solar-driven calcination were investigated. Then, four binders were prepared by mixing slaked dolomite (obtained from the hydration of solar calcined dolomite) with either blast furnace slag or coal fly ash as supplementary cementitious materials. The binders were hydrated for curing times ranging from 7 to 56 days. X-ray fluorescence, X-ray diffraction and combined differential thermal and thermogravimetric analyses were employed as characterisation techniques both to analyse the chemical composition of starting materials and to investigate the evolution of the hydration in the four systems.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao IRIS Cnrarrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    CNR ExploRA
    Article . 2022
    Data sources: CNR ExploRA
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Solar Energy
    Article . 2022 . Peer-reviewed
    License: Elsevier TDM
    Data sources: Crossref
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    addClaim

    This Research product is the result of merged Research products in OpenAIRE.

    You have already added works in your ORCID record related to the merged Research product.
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao IRIS Cnrarrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      CNR ExploRA
      Article . 2022
      Data sources: CNR ExploRA
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Solar Energy
      Article . 2022 . Peer-reviewed
      License: Elsevier TDM
      Data sources: Crossref
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      addClaim

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Chiodo E.; Lauria D.; Mottola F.; Proto D.; +3 Authors

    Battery participation in the service of power system frequency regulation is universally recognized as a viable means for counteracting the dramatic impact of the increasing utilization of renewable energy sources. One of the most complex aspects, in both the planning and operation stage, is the adequate characterization of the dynamic variation of the state of charge of the battery in view of lifetime preservation as well as the adequate participation in the regulation task. Since the power system frequency, which is the input of the battery regulation service, is inherently of a stochastic nature, it is easy to argue that the most proper methodology for addressing this complex issue is that of the theory of stochastic processes. In the first part of the paper, a preliminary characterization of the power system frequency is presented by showing that with an optimal degree of approximation it can be regarded as an Ornstein–Uhlenbeck process. Some considerations for guaranteeing desirable performances of the control strategy are performed by assuming that the battery-regulating power depending on the frequency can be described by means of a Wiener process. In the second part of the paper, more realistically, the regulating power due to power system changes is described as an Ornstein–Uhlenbeck or an exponential shot noise process driven by a homogeneous Poisson process depending on the frequency response features requested of the battery. Because of that, the battery state of charge is modeled as the output of a dynamic filter having this exponential shot noise process as input and its characterization constitutes the central role for the correct characterization of the battery life. Numerical simulations are carried out for demonstrating the goodness and the applicability of the proposed probabilistic approach.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2022 . Peer-reviewed
    License: CC BY
    Data sources: Crossref
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2022
    Data sources: DOAJ
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2022 . Peer-reviewed
      License: CC BY
      Data sources: Crossref
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2022
      Data sources: DOAJ
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      addClaim

      This Research product is the result of merged Research products in OpenAIRE.

      You have already added works in your ORCID record related to the merged Research product.
  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Chiodo E.; Lauria D.; Mottola F.; Proto D.; +3 Authors

    Battery participation in the service of power system frequency regulation is universally recognized as a viable means for counteracting the dramatic impact of the increasing utilization of renewable energy sources. One of the most complex aspects, in both the planning and operation stage, is the adequate characterization of the dynamic variation of the state of charge of the battery in view of lifetime preservation as well as the adequate participation in the regulation task. Since the power system frequency, which is the input of the battery regulation service, is inherently of a stochastic nature, it is easy to argue that the most proper methodology for addressing this complex issue is that of the theory of stochastic processes. In the first part of the paper, a preliminary characterization of the power system frequency is presented by showing that with an optimal degree of approximation it can be regarded as an Ornstein–Uhlenbeck process. Some considerations for guaranteeing desirable performances of the control strategy are performed by assuming that the battery-regulating power depending on the frequency can be described by means of a Wiener process. In the second part of the paper, more realistically, the regulating power due to power system changes is described as an Ornstein–Uhlenbeck or an exponential shot noise process driven by a homogeneous Poisson process depending on the frequency response features requested of the battery. Because of that, the battery state of charge is modeled as the output of a dynamic filter having this exponential shot noise process as input and its characterization constitutes the central role for the correct characterization of the battery life. Numerical simulations are carried out for demonstrating the goodness and the applicability of the proposed probabilistic approach.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2022 . Peer-reviewed
    License: CC BY
    Data sources: Crossref
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2022
    Data sources: DOAJ
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2022 . Peer-reviewed
      License: CC BY
      Data sources: Crossref
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2022
      Data sources: DOAJ
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Coppola, Marino; Guerriero, Pierluigi; Dannier, Adolfo; Daliento, Santolo; +1 Authors

    In this paper a grid-tied photovoltaic (PV) cascaded H-bridge (CHB) inverter with embedded storage units is proposed. The multi-input single-output inverter architecture allows a distributed maximum power point tracking (DMPPT) approach, thus mitigating the mismatch effects. The energy storage units (ESUs) embedded at each dc-link provides more flexibility to the power circuit compensating for the inherent variability of the PV sources. The proposed power system ensures a continuous power supply to the grid also in case of PV power fluctuations due to irradiance conditions as well as to the MPPT. In particular, the presence of a storage element allows a voltage sweep on the PV source to be implemented, thus guaranteeing the maximization of PV energy harvesting, with no detrimental effect on the power delivery to the utility network. The numerical results, carried out on a single-phase nineteen-level PV CHB inverter, reveal the improved performance of the proposed design and control technique.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Archivio della ricer...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    https://doi.org/10.1109/rtsi50...
    Conference object . 2021 . Peer-reviewed
    License: IEEE Copyright
    Data sources: Crossref
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    Authors: Coppola, Marino; Guerriero, Pierluigi; Dannier, Adolfo; Daliento, Santolo; +1 Authors

    In this paper a grid-tied photovoltaic (PV) cascaded H-bridge (CHB) inverter with embedded storage units is proposed. The multi-input single-output inverter architecture allows a distributed maximum power point tracking (DMPPT) approach, thus mitigating the mismatch effects. The energy storage units (ESUs) embedded at each dc-link provides more flexibility to the power circuit compensating for the inherent variability of the PV sources. The proposed power system ensures a continuous power supply to the grid also in case of PV power fluctuations due to irradiance conditions as well as to the MPPT. In particular, the presence of a storage element allows a voltage sweep on the PV source to be implemented, thus guaranteeing the maximization of PV energy harvesting, with no detrimental effect on the power delivery to the utility network. The numerical results, carried out on a single-phase nineteen-level PV CHB inverter, reveal the improved performance of the proposed design and control technique.

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    https://doi.org/10.1109/rtsi50...
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    Authors: Skrydstrup, Julie; Löwe, Roland; Gregersen, Ida Bülow; Koetse, Mark; +3 Authors

    Nature-based solutions may actively reduce hydro-meteorological risks in urban areas as a part of climate change adaptation. However, the main reason for the increasing uptake of this type of solution is their many benefits for the local inhabitants, including recreational value. Previous studies on recreational value focus on studies of existing nature sites that are often much larger than what is considered as new NBS for flood adaptation studies in urban areas. We thus prioritized studies with smaller areas and nature types suitable for urban flood adaptation and divided them into four common nature types for urban flood adaptation: sustainable urban drainage systems, city parks, nature areas and rivers. We identified 23 primary valuation studies, including both stated and revealed preference studies, and derived two value transfer functions based on meta-regression analysis on existing areas. We investigated trends between values and variables and found that for the purpose of planning of new NBS the size of NBS and population density were determining factors of recreational value. For existing NBS the maximum travelling distance may be included as well. We find that existing state-of-the-art studies overestimate the recreational with more than a factor of 4 for NBS sizes below 5 ha. Our results are valid in a European context for nature-based solutions below 250 ha and can be applied across different NBS types and sizes.

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    Authors: Skrydstrup, Julie; Löwe, Roland; Gregersen, Ida Bülow; Koetse, Mark; +3 Authors

    Nature-based solutions may actively reduce hydro-meteorological risks in urban areas as a part of climate change adaptation. However, the main reason for the increasing uptake of this type of solution is their many benefits for the local inhabitants, including recreational value. Previous studies on recreational value focus on studies of existing nature sites that are often much larger than what is considered as new NBS for flood adaptation studies in urban areas. We thus prioritized studies with smaller areas and nature types suitable for urban flood adaptation and divided them into four common nature types for urban flood adaptation: sustainable urban drainage systems, city parks, nature areas and rivers. We identified 23 primary valuation studies, including both stated and revealed preference studies, and derived two value transfer functions based on meta-regression analysis on existing areas. We investigated trends between values and variables and found that for the purpose of planning of new NBS the size of NBS and population density were determining factors of recreational value. For existing NBS the maximum travelling distance may be included as well. We find that existing state-of-the-art studies overestimate the recreational with more than a factor of 4 for NBS sizes below 5 ha. Our results are valid in a European context for nature-based solutions below 250 ha and can be applied across different NBS types and sizes.

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    Authors: Assunta Borzacchiello; Luca Cirillo; Adriana Greco; Claudia Masselli;

    Solid-state refrigeration based on the caloric effects has recently received widespread consideration because of its high efficiency and environmental protection. Compared with other solid-state refrigeration technologies, the elastocaloric effect-based one has great application potential. The elastoCaloric Effect (eCE) is defined as the reversible adiabatic temperature change (ΔTad) and the reversible isothermal entropy change (ΔST) in Shape Memory Alloys (SMA), following a variation in the mechanical field applied. To date, the elastocaloric materials, considered as benchmark, since offering the best compromise between thermal and mechanical performances are represented by the NiTi binary alloys.

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    Applied Thermal Engineering
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    Authors: Assunta Borzacchiello; Luca Cirillo; Adriana Greco; Claudia Masselli;

    Solid-state refrigeration based on the caloric effects has recently received widespread consideration because of its high efficiency and environmental protection. Compared with other solid-state refrigeration technologies, the elastocaloric effect-based one has great application potential. The elastoCaloric Effect (eCE) is defined as the reversible adiabatic temperature change (ΔTad) and the reversible isothermal entropy change (ΔST) in Shape Memory Alloys (SMA), following a variation in the mechanical field applied. To date, the elastocaloric materials, considered as benchmark, since offering the best compromise between thermal and mechanical performances are represented by the NiTi binary alloys.

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    Applied Thermal Engineering
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    Authors: Elena Cervelli; Pier Francesco Recchi; Ester Scotto di Perta; Stefania Pindozzi;

    In the last two centuries, land-use change (LUC) has been the most important direct change driver for terrestrial ecosystems. In contrast with the consequent ecosystem degradation, forward-looking spatial policies and target landscape and land-use planning processes are needed from a sustainability perspective. The present paper proposes a framework of action, including different landscape-planning and ecological approaches: from spatial modelling to recognize LUC and build different scenarios, to ecosystem service (ES) assessment to evaluate possible environmental impacts. Three different scenarios were explored: Trend, No Tillage, and Energy crops. The sediment delivery ratio and carbon storage and sequestration ESs were assessed and compared for each scenario. The results show that regional development in line with past trends could lead to further land degradation (with ES value losses, in a decade, greater than 5%). Instead, the two scenarios proposed in compliance with EU policies could bring benefits, if only those related to moderate LUCs and respecting the naturally grass-vegetated land. The aim of the paper is to support decision makers and local communities in the landscape planning landscape planning process. From the local to global scale, guided and shared LUC management allows us to implement sustainable development, based not only on a deep knowledge of the physical environment but also of social and economic issues.

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    Authors: Elena Cervelli; Pier Francesco Recchi; Ester Scotto di Perta; Stefania Pindozzi;

    In the last two centuries, land-use change (LUC) has been the most important direct change driver for terrestrial ecosystems. In contrast with the consequent ecosystem degradation, forward-looking spatial policies and target landscape and land-use planning processes are needed from a sustainability perspective. The present paper proposes a framework of action, including different landscape-planning and ecological approaches: from spatial modelling to recognize LUC and build different scenarios, to ecosystem service (ES) assessment to evaluate possible environmental impacts. Three different scenarios were explored: Trend, No Tillage, and Energy crops. The sediment delivery ratio and carbon storage and sequestration ESs were assessed and compared for each scenario. The results show that regional development in line with past trends could lead to further land degradation (with ES value losses, in a decade, greater than 5%). Instead, the two scenarios proposed in compliance with EU policies could bring benefits, if only those related to moderate LUCs and respecting the naturally grass-vegetated land. The aim of the paper is to support decision makers and local communities in the landscape planning landscape planning process. From the local to global scale, guided and shared LUC management allows us to implement sustainable development, based not only on a deep knowledge of the physical environment but also of social and economic issues.

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    Authors: Subba, F.; Coster, D. P.; Xiang, L.; Militello, F.; +10 Authors

    A double-null configuration is being considered for the EU-DEMO, due to its potential benefits for power exhaust arising from the use of two active divertors and magnetically disconnected low- and high-field sides. Using systematic parameter scans in fluid simulations, we have investigated the divertor power exhaust in the EU-DEMO in a connected double-null configuration, and compared the edge plasma properties to those obtained in a single-null configuration under detached conditions anticipated for reactor operation. Neglecting drift effects and kinetic behaviour of the neutrals, no clear benefits of the double-null configuration could yet be identified for the radiation pattern and power mitigation on open field lines. Future work should address the aforementioned physics as well as the effect of the additional X-point on core radiation.

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    Nuclear Materials and Energy
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    Authors: Subba, F.; Coster, D. P.; Xiang, L.; Militello, F.; +10 Authors

    A double-null configuration is being considered for the EU-DEMO, due to its potential benefits for power exhaust arising from the use of two active divertors and magnetically disconnected low- and high-field sides. Using systematic parameter scans in fluid simulations, we have investigated the divertor power exhaust in the EU-DEMO in a connected double-null configuration, and compared the edge plasma properties to those obtained in a single-null configuration under detached conditions anticipated for reactor operation. Neglecting drift effects and kinetic behaviour of the neutrals, no clear benefits of the double-null configuration could yet be identified for the radiation pattern and power mitigation on open field lines. Future work should address the aforementioned physics as well as the effect of the additional X-point on core radiation.

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    Authors: Marc van den Homberg; Aklilu Teklesadik; Dennis L.J. van den Berg; Gabriela Guimarães Nobre; +3 Authors

    Food insecurity is a growing concern due to man-made conflicts, climate change, and economic downturns. Forecasting the state of food insecurity is essential to be able to trigger early actions, for example, by humanitarian actors. To measure the actual state of food insecurity, expert and consensus-based approaches and surveys are currently used. Both require substantial manpower, time, and budget. This paper introduces an extreme gradient-boosting machine learning model to forecast monthly transitions in the state of food security in Ethiopia, at a spatial granularity of livelihood zones, and for lead times of one to 12 months, using open-source data. The transition in the state of food security, hereafter referred to as predictand, is represented by the Integrated Food Security Phase Classification Data. From 19 categories of datasets, 130 variables were derived and used as predictors of the transition in the state of food security. The predictors represent changes in climate and land, market, conflict, infrastructure, demographics and livelihood zone characteristics. The most relevant predictors are found to be food security history and surface soil moisture. Overall, the model performs best for forecasting Deteriorations and Improvements in the state of food security compared to the baselines. The proposed method performs (F1 macro score) at least twice as well as the best baseline (a dummy classifier) for a Deterioration. The model performs better when forecasting long-term (7 months; F1 macro average = 0.61) compared to short-term (3 months; F1 macro average = 0.51). Combining machine learning, Integrated Phase Classification (IPC) ratings from monitoring systems, and open data can add value to existing consensus-based forecasting approaches as this combination provides longer lead times and more regular updates. Our approach can also be transferred to other countries as most of the data on the predictors are openly available from global data repositories.

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    Authors: Marc van den Homberg; Aklilu Teklesadik; Dennis L.J. van den Berg; Gabriela Guimarães Nobre; +3 Authors

    Food insecurity is a growing concern due to man-made conflicts, climate change, and economic downturns. Forecasting the state of food insecurity is essential to be able to trigger early actions, for example, by humanitarian actors. To measure the actual state of food insecurity, expert and consensus-based approaches and surveys are currently used. Both require substantial manpower, time, and budget. This paper introduces an extreme gradient-boosting machine learning model to forecast monthly transitions in the state of food security in Ethiopia, at a spatial granularity of livelihood zones, and for lead times of one to 12 months, using open-source data. The transition in the state of food security, hereafter referred to as predictand, is represented by the Integrated Food Security Phase Classification Data. From 19 categories of datasets, 130 variables were derived and used as predictors of the transition in the state of food security. The predictors represent changes in climate and land, market, conflict, infrastructure, demographics and livelihood zone characteristics. The most relevant predictors are found to be food security history and surface soil moisture. Overall, the model performs best for forecasting Deteriorations and Improvements in the state of food security compared to the baselines. The proposed method performs (F1 macro score) at least twice as well as the best baseline (a dummy classifier) for a Deterioration. The model performs better when forecasting long-term (7 months; F1 macro average = 0.61) compared to short-term (3 months; F1 macro average = 0.51). Combining machine learning, Integrated Phase Classification (IPC) ratings from monitoring systems, and open data can add value to existing consensus-based forecasting approaches as this combination provides longer lead times and more regular updates. Our approach can also be transferred to other countries as most of the data on the predictors are openly available from global data repositories.

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    Authors: Valeria D'Ambrosio; Alessandro Sgobbo;

    The paper presents the intermediate results of the design experimentation of a Public Housing development in which the Renewable Energy Community model is an opportunity for energy transition but also for the needs of social inclusion and collaboration, which characterise the complex conditions of contemporary housing. Demonstrating the transcalar and multifunctional effectiveness of RECs incentivises their implementation, especially when a complex demanding framework is confronted with limitedly available resources. Hence, through a systemic approach, simulative methods and impact indicators, the extent of the contribution offered by the REC model was verified not only in terms of decarbonisation and climate neutrality but as an opportunity for eco-social regeneration.

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    Authors: Valeria D'Ambrosio; Alessandro Sgobbo;

    The paper presents the intermediate results of the design experimentation of a Public Housing development in which the Renewable Energy Community model is an opportunity for energy transition but also for the needs of social inclusion and collaboration, which characterise the complex conditions of contemporary housing. Demonstrating the transcalar and multifunctional effectiveness of RECs incentivises their implementation, especially when a complex demanding framework is confronted with limitedly available resources. Hence, through a systemic approach, simulative methods and impact indicators, the extent of the contribution offered by the REC model was verified not only in terms of decarbonisation and climate neutrality but as an opportunity for eco-social regeneration.

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Paul Palmay; Cesar Puente; Diego Barzallo; Joan Carles Bruno;

    Currently, the pyrolysis process is an important technology for the final treatment of plastic waste worldwide. For this reason, knowing in detail the chemical process and the thermodynamics that accompany cracking reactions is of utmost importance. The present study aims to determine the thermodynamic parameters of the degradation process of conventional thermoplastics (polystyrene (PS), polyethylene terephthalate (PET), high-density polyethylene (HDPE), polypropylene (PP) and polyvinyl chloride (PVC)) from the study of their chemical kinetics by thermogravimetric analysis (TG). Non-isothermal thermogravimetry was performed at three heating rates from room temperature to 550 °C with an inert nitrogen atmosphere with a flow of 20 mL min−1. Once the TG data is obtained, an analysis is carried out with the isoconversional models of Friedman (FR), Kissinger–Akahira–Sunose (KAS), and Flynn–Wall–Ozawa (FWO) in order to determine the one that best fits the experimental data, and with this, the calculation of the activation energy and the pre-exponential factor is performed. The validation of the model was carried out using the correlation factor, determining that the KAS model is the one that best adjusts for the post-consumer thermoplastic degradation process at the three heating rates. With the use of the kinetic parameters, the variation of the Gibbs free energy is determined in each of the cases, where it is necessary that for structures containing aromatic groups a lower energy is presented, which implies a relative ease of degradation compared to the linear structures.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Polymersarrow_drop_down
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    Polymers
    Article . 2021 . Peer-reviewed
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    Polymers
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    PubMed Central
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    Polymers
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      Polymers
      Article . 2021 . Peer-reviewed
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      Other literature type . 2021
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      Polymers
      Article . 2021
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    Authors: Paul Palmay; Cesar Puente; Diego Barzallo; Joan Carles Bruno;

    Currently, the pyrolysis process is an important technology for the final treatment of plastic waste worldwide. For this reason, knowing in detail the chemical process and the thermodynamics that accompany cracking reactions is of utmost importance. The present study aims to determine the thermodynamic parameters of the degradation process of conventional thermoplastics (polystyrene (PS), polyethylene terephthalate (PET), high-density polyethylene (HDPE), polypropylene (PP) and polyvinyl chloride (PVC)) from the study of their chemical kinetics by thermogravimetric analysis (TG). Non-isothermal thermogravimetry was performed at three heating rates from room temperature to 550 °C with an inert nitrogen atmosphere with a flow of 20 mL min−1. Once the TG data is obtained, an analysis is carried out with the isoconversional models of Friedman (FR), Kissinger–Akahira–Sunose (KAS), and Flynn–Wall–Ozawa (FWO) in order to determine the one that best fits the experimental data, and with this, the calculation of the activation energy and the pre-exponential factor is performed. The validation of the model was carried out using the correlation factor, determining that the KAS model is the one that best adjusts for the post-consumer thermoplastic degradation process at the three heating rates. With the use of the kinetic parameters, the variation of the Gibbs free energy is determined in each of the cases, where it is necessary that for structures containing aromatic groups a lower energy is presented, which implies a relative ease of degradation compared to the linear structures.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Polymersarrow_drop_down
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    Polymers
    Article . 2021 . Peer-reviewed
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    PubMed Central
    Other literature type . 2021
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    Polymers
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      Polymers
      Article . 2021 . Peer-reviewed
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Marroccoli M.; Ibris N.; Telesca A.; Tregambi C.; +5 Authors

    Dolomite-based binders are characterised by interesting technical and environmental features. For their synthesis, sources of both CaO and MgO are required. The idea developed in this work is to couple the synthesis of dolomite-based binders, starting from a natural dolomite, through the concept of concentrated solar energy (needed to drive the endothermal dolomite calcination process) in fluidised bed reactors. To this end, a fluidised bed system, where the concentrated solar radiation is mimicked by the use of Xe-lamps (short-arc), has been set up and operated. Natural dolomite (sieved in the 420-590 ?m size range) was calcined at a nominal temperature of 850 °C, and bed temperature profiles during solar-driven calcination were investigated. Then, four binders were prepared by mixing slaked dolomite (obtained from the hydration of solar calcined dolomite) with either blast furnace slag or coal fly ash as supplementary cementitious materials. The binders were hydrated for curing times ranging from 7 to 56 days. X-ray fluorescence, X-ray diffraction and combined differential thermal and thermogravimetric analyses were employed as characterisation techniques both to analyse the chemical composition of starting materials and to investigate the evolution of the hydration in the four systems.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao IRIS Cnrarrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    CNR ExploRA
    Article . 2022
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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Solar Energy
    Article . 2022 . Peer-reviewed
    License: Elsevier TDM
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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao IRIS Cnrarrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Solar Energy
      Article . 2022 . Peer-reviewed
      License: Elsevier TDM
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Marroccoli M.; Ibris N.; Telesca A.; Tregambi C.; +5 Authors

    Dolomite-based binders are characterised by interesting technical and environmental features. For their synthesis, sources of both CaO and MgO are required. The idea developed in this work is to couple the synthesis of dolomite-based binders, starting from a natural dolomite, through the concept of concentrated solar energy (needed to drive the endothermal dolomite calcination process) in fluidised bed reactors. To this end, a fluidised bed system, where the concentrated solar radiation is mimicked by the use of Xe-lamps (short-arc), has been set up and operated. Natural dolomite (sieved in the 420-590 ?m size range) was calcined at a nominal temperature of 850 °C, and bed temperature profiles during solar-driven calcination were investigated. Then, four binders were prepared by mixing slaked dolomite (obtained from the hydration of solar calcined dolomite) with either blast furnace slag or coal fly ash as supplementary cementitious materials. The binders were hydrated for curing times ranging from 7 to 56 days. X-ray fluorescence, X-ray diffraction and combined differential thermal and thermogravimetric analyses were employed as characterisation techniques both to analyse the chemical composition of starting materials and to investigate the evolution of the hydration in the four systems.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao IRIS Cnrarrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    CNR ExploRA
    Article . 2022
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    Authors: Chiodo E.; Lauria D.; Mottola F.; Proto D.; +3 Authors

    Battery participation in the service of power system frequency regulation is universally recognized as a viable means for counteracting the dramatic impact of the increasing utilization of renewable energy sources. One of the most complex aspects, in both the planning and operation stage, is the adequate characterization of the dynamic variation of the state of charge of the battery in view of lifetime preservation as well as the adequate participation in the regulation task. Since the power system frequency, which is the input of the battery regulation service, is inherently of a stochastic nature, it is easy to argue that the most proper methodology for addressing this complex issue is that of the theory of stochastic processes. In the first part of the paper, a preliminary characterization of the power system frequency is presented by showing that with an optimal degree of approximation it can be regarded as an Ornstein–Uhlenbeck process. Some considerations for guaranteeing desirable performances of the control strategy are performed by assuming that the battery-regulating power depending on the frequency can be described by means of a Wiener process. In the second part of the paper, more realistically, the regulating power due to power system changes is described as an Ornstein–Uhlenbeck or an exponential shot noise process driven by a homogeneous Poisson process depending on the frequency response features requested of the battery. Because of that, the battery state of charge is modeled as the output of a dynamic filter having this exponential shot noise process as input and its characterization constitutes the central role for the correct characterization of the battery life. Numerical simulations are carried out for demonstrating the goodness and the applicability of the proposed probabilistic approach.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
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      Energies
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      Energies
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    Authors: Chiodo E.; Lauria D.; Mottola F.; Proto D.; +3 Authors

    Battery participation in the service of power system frequency regulation is universally recognized as a viable means for counteracting the dramatic impact of the increasing utilization of renewable energy sources. One of the most complex aspects, in both the planning and operation stage, is the adequate characterization of the dynamic variation of the state of charge of the battery in view of lifetime preservation as well as the adequate participation in the regulation task. Since the power system frequency, which is the input of the battery regulation service, is inherently of a stochastic nature, it is easy to argue that the most proper methodology for addressing this complex issue is that of the theory of stochastic processes. In the first part of the paper, a preliminary characterization of the power system frequency is presented by showing that with an optimal degree of approximation it can be regarded as an Ornstein–Uhlenbeck process. Some considerations for guaranteeing desirable performances of the control strategy are performed by assuming that the battery-regulating power depending on the frequency can be described by means of a Wiener process. In the second part of the paper, more realistically, the regulating power due to power system changes is described as an Ornstein–Uhlenbeck or an exponential shot noise process driven by a homogeneous Poisson process depending on the frequency response features requested of the battery. Because of that, the battery state of charge is modeled as the output of a dynamic filter having this exponential shot noise process as input and its characterization constitutes the central role for the correct characterization of the battery life. Numerical simulations are carried out for demonstrating the goodness and the applicability of the proposed probabilistic approach.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2022 . Peer-reviewed
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    Energies
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      Energies
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      Energies
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Coppola, Marino; Guerriero, Pierluigi; Dannier, Adolfo; Daliento, Santolo; +1 Authors

    In this paper a grid-tied photovoltaic (PV) cascaded H-bridge (CHB) inverter with embedded storage units is proposed. The multi-input single-output inverter architecture allows a distributed maximum power point tracking (DMPPT) approach, thus mitigating the mismatch effects. The energy storage units (ESUs) embedded at each dc-link provides more flexibility to the power circuit compensating for the inherent variability of the PV sources. The proposed power system ensures a continuous power supply to the grid also in case of PV power fluctuations due to irradiance conditions as well as to the MPPT. In particular, the presence of a storage element allows a voltage sweep on the PV source to be implemented, thus guaranteeing the maximization of PV energy harvesting, with no detrimental effect on the power delivery to the utility network. The numerical results, carried out on a single-phase nineteen-level PV CHB inverter, reveal the improved performance of the proposed design and control technique.

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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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    https://doi.org/10.1109/rtsi50...
    Conference object . 2021 . Peer-reviewed
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    Authors: Coppola, Marino; Guerriero, Pierluigi; Dannier, Adolfo; Daliento, Santolo; +1 Authors

    In this paper a grid-tied photovoltaic (PV) cascaded H-bridge (CHB) inverter with embedded storage units is proposed. The multi-input single-output inverter architecture allows a distributed maximum power point tracking (DMPPT) approach, thus mitigating the mismatch effects. The energy storage units (ESUs) embedded at each dc-link provides more flexibility to the power circuit compensating for the inherent variability of the PV sources. The proposed power system ensures a continuous power supply to the grid also in case of PV power fluctuations due to irradiance conditions as well as to the MPPT. In particular, the presence of a storage element allows a voltage sweep on the PV source to be implemented, thus guaranteeing the maximization of PV energy harvesting, with no detrimental effect on the power delivery to the utility network. The numerical results, carried out on a single-phase nineteen-level PV CHB inverter, reveal the improved performance of the proposed design and control technique.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Archivio della ricer...arrow_drop_down
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    https://doi.org/10.1109/rtsi50...
    Conference object . 2021 . Peer-reviewed
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    Authors: Skrydstrup, Julie; Löwe, Roland; Gregersen, Ida Bülow; Koetse, Mark; +3 Authors

    Nature-based solutions may actively reduce hydro-meteorological risks in urban areas as a part of climate change adaptation. However, the main reason for the increasing uptake of this type of solution is their many benefits for the local inhabitants, including recreational value. Previous studies on recreational value focus on studies of existing nature sites that are often much larger than what is considered as new NBS for flood adaptation studies in urban areas. We thus prioritized studies with smaller areas and nature types suitable for urban flood adaptation and divided them into four common nature types for urban flood adaptation: sustainable urban drainage systems, city parks, nature areas and rivers. We identified 23 primary valuation studies, including both stated and revealed preference studies, and derived two value transfer functions based on meta-regression analysis on existing areas. We investigated trends between values and variables and found that for the purpose of planning of new NBS the size of NBS and population density were determining factors of recreational value. For existing NBS the maximum travelling distance may be included as well. We find that existing state-of-the-art studies overestimate the recreational with more than a factor of 4 for NBS sizes below 5 ha. Our results are valid in a European context for nature-based solutions below 250 ha and can be applied across different NBS types and sizes.

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    Journal of Environmental Management
    Article . 2022 . Peer-reviewed
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    ZENODO
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    ZENODO
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    ZENODO
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    http://dx.doi.org/10.1016/j.je...
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      Journal of Environmental Management
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      http://dx.doi.org/10.1016/j.je...
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    Authors: Skrydstrup, Julie; Löwe, Roland; Gregersen, Ida Bülow; Koetse, Mark; +3 Authors

    Nature-based solutions may actively reduce hydro-meteorological risks in urban areas as a part of climate change adaptation. However, the main reason for the increasing uptake of this type of solution is their many benefits for the local inhabitants, including recreational value. Previous studies on recreational value focus on studies of existing nature sites that are often much larger than what is considered as new NBS for flood adaptation studies in urban areas. We thus prioritized studies with smaller areas and nature types suitable for urban flood adaptation and divided them into four common nature types for urban flood adaptation: sustainable urban drainage systems, city parks, nature areas and rivers. We identified 23 primary valuation studies, including both stated and revealed preference studies, and derived two value transfer functions based on meta-regression analysis on existing areas. We investigated trends between values and variables and found that for the purpose of planning of new NBS the size of NBS and population density were determining factors of recreational value. For existing NBS the maximum travelling distance may be included as well. We find that existing state-of-the-art studies overestimate the recreational with more than a factor of 4 for NBS sizes below 5 ha. Our results are valid in a European context for nature-based solutions below 250 ha and can be applied across different NBS types and sizes.

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    Journal of Environmental Management
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      Journal of Environmental Management
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    Authors: Assunta Borzacchiello; Luca Cirillo; Adriana Greco; Claudia Masselli;

    Solid-state refrigeration based on the caloric effects has recently received widespread consideration because of its high efficiency and environmental protection. Compared with other solid-state refrigeration technologies, the elastocaloric effect-based one has great application potential. The elastoCaloric Effect (eCE) is defined as the reversible adiabatic temperature change (ΔTad) and the reversible isothermal entropy change (ΔST) in Shape Memory Alloys (SMA), following a variation in the mechanical field applied. To date, the elastocaloric materials, considered as benchmark, since offering the best compromise between thermal and mechanical performances are represented by the NiTi binary alloys.

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    Applied Thermal Engineering
    Article . 2023 . Peer-reviewed
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    Authors: Assunta Borzacchiello; Luca Cirillo; Adriana Greco; Claudia Masselli;

    Solid-state refrigeration based on the caloric effects has recently received widespread consideration because of its high efficiency and environmental protection. Compared with other solid-state refrigeration technologies, the elastocaloric effect-based one has great application potential. The elastoCaloric Effect (eCE) is defined as the reversible adiabatic temperature change (ΔTad) and the reversible isothermal entropy change (ΔST) in Shape Memory Alloys (SMA), following a variation in the mechanical field applied. To date, the elastocaloric materials, considered as benchmark, since offering the best compromise between thermal and mechanical performances are represented by the NiTi binary alloys.

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    Applied Thermal Engineering
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    Authors: Elena Cervelli; Pier Francesco Recchi; Ester Scotto di Perta; Stefania Pindozzi;

    In the last two centuries, land-use change (LUC) has been the most important direct change driver for terrestrial ecosystems. In contrast with the consequent ecosystem degradation, forward-looking spatial policies and target landscape and land-use planning processes are needed from a sustainability perspective. The present paper proposes a framework of action, including different landscape-planning and ecological approaches: from spatial modelling to recognize LUC and build different scenarios, to ecosystem service (ES) assessment to evaluate possible environmental impacts. Three different scenarios were explored: Trend, No Tillage, and Energy crops. The sediment delivery ratio and carbon storage and sequestration ESs were assessed and compared for each scenario. The results show that regional development in line with past trends could lead to further land degradation (with ES value losses, in a decade, greater than 5%). Instead, the two scenarios proposed in compliance with EU policies could bring benefits, if only those related to moderate LUCs and respecting the naturally grass-vegetated land. The aim of the paper is to support decision makers and local communities in the landscape planning landscape planning process. From the local to global scale, guided and shared LUC management allows us to implement sustainable development, based not only on a deep knowledge of the physical environment but also of social and economic issues.

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    Authors: Elena Cervelli; Pier Francesco Recchi; Ester Scotto di Perta; Stefania Pindozzi;

    In the last two centuries, land-use change (LUC) has been the most important direct change driver for terrestrial ecosystems. In contrast with the consequent ecosystem degradation, forward-looking spatial policies and target landscape and land-use planning processes are needed from a sustainability perspective. The present paper proposes a framework of action, including different landscape-planning and ecological approaches: from spatial modelling to recognize LUC and build different scenarios, to ecosystem service (ES) assessment to evaluate possible environmental impacts. Three different scenarios were explored: Trend, No Tillage, and Energy crops. The sediment delivery ratio and carbon storage and sequestration ESs were assessed and compared for each scenario. The results show that regional development in line with past trends could lead to further land degradation (with ES value losses, in a decade, greater than 5%). Instead, the two scenarios proposed in compliance with EU policies could bring benefits, if only those related to moderate LUCs and respecting the naturally grass-vegetated land. The aim of the paper is to support decision makers and local communities in the landscape planning landscape planning process. From the local to global scale, guided and shared LUC management allows us to implement sustainable development, based not only on a deep knowledge of the physical environment but also of social and economic issues.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Landarrow_drop_down
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    Authors: Subba, F.; Coster, D. P.; Xiang, L.; Militello, F.; +10 Authors

    A double-null configuration is being considered for the EU-DEMO, due to its potential benefits for power exhaust arising from the use of two active divertors and magnetically disconnected low- and high-field sides. Using systematic parameter scans in fluid simulations, we have investigated the divertor power exhaust in the EU-DEMO in a connected double-null configuration, and compared the edge plasma properties to those obtained in a single-null configuration under detached conditions anticipated for reactor operation. Neglecting drift effects and kinetic behaviour of the neutrals, no clear benefits of the double-null configuration could yet be identified for the radiation pattern and power mitigation on open field lines. Future work should address the aforementioned physics as well as the effect of the additional X-point on core radiation.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Publications Open Re...arrow_drop_down
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    Nuclear Materials and Energy
    Article . 2021 . Peer-reviewed
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    Nuclear Materials and Energy
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    Nuclear Materials and Energy
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    Nuclear Materials and Energy
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    Nuclear Materials and Energy
    Article . 2021 . Peer-reviewed
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    http://dx.doi.org/10.1016/j.nm...
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      Nuclear Materials and Energy
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      http://dx.doi.org/10.1016/j.nm...
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    Authors: Subba, F.; Coster, D. P.; Xiang, L.; Militello, F.; +10 Authors

    A double-null configuration is being considered for the EU-DEMO, due to its potential benefits for power exhaust arising from the use of two active divertors and magnetically disconnected low- and high-field sides. Using systematic parameter scans in fluid simulations, we have investigated the divertor power exhaust in the EU-DEMO in a connected double-null configuration, and compared the edge plasma properties to those obtained in a single-null configuration under detached conditions anticipated for reactor operation. Neglecting drift effects and kinetic behaviour of the neutrals, no clear benefits of the double-null configuration could yet be identified for the radiation pattern and power mitigation on open field lines. Future work should address the aforementioned physics as well as the effect of the additional X-point on core radiation.

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    Nuclear Materials and Energy
    Article . 2021 . Peer-reviewed
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    Nuclear Materials and Energy
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    Nuclear Materials and Energy
    Article . 2021
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    Nuclear Materials and Energy
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    Nuclear Materials and Energy
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    Nuclear Materials and Energy
    Article . 2021 . Peer-reviewed
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    http://dx.doi.org/10.1016/j.nm...
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      Nuclear Materials and Energy
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      Nuclear Materials and Energy
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      http://dx.doi.org/10.1016/j.nm...
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    Authors: Marc van den Homberg; Aklilu Teklesadik; Dennis L.J. van den Berg; Gabriela Guimarães Nobre; +3 Authors

    Food insecurity is a growing concern due to man-made conflicts, climate change, and economic downturns. Forecasting the state of food insecurity is essential to be able to trigger early actions, for example, by humanitarian actors. To measure the actual state of food insecurity, expert and consensus-based approaches and surveys are currently used. Both require substantial manpower, time, and budget. This paper introduces an extreme gradient-boosting machine learning model to forecast monthly transitions in the state of food security in Ethiopia, at a spatial granularity of livelihood zones, and for lead times of one to 12 months, using open-source data. The transition in the state of food security, hereafter referred to as predictand, is represented by the Integrated Food Security Phase Classification Data. From 19 categories of datasets, 130 variables were derived and used as predictors of the transition in the state of food security. The predictors represent changes in climate and land, market, conflict, infrastructure, demographics and livelihood zone characteristics. The most relevant predictors are found to be food security history and surface soil moisture. Overall, the model performs best for forecasting Deteriorations and Improvements in the state of food security compared to the baselines. The proposed method performs (F1 macro score) at least twice as well as the best baseline (a dummy classifier) for a Deterioration. The model performs better when forecasting long-term (7 months; F1 macro average = 0.61) compared to short-term (3 months; F1 macro average = 0.51). Combining machine learning, Integrated Phase Classification (IPC) ratings from monitoring systems, and open data can add value to existing consensus-based forecasting approaches as this combination provides longer lead times and more regular updates. Our approach can also be transferred to other countries as most of the data on the predictors are openly available from global data repositories.

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    The Science of The Total Environment
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    The Science of The Total Environment
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      The Science of The Total Environment
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    Authors: Marc van den Homberg; Aklilu Teklesadik; Dennis L.J. van den Berg; Gabriela Guimarães Nobre; +3 Authors

    Food insecurity is a growing concern due to man-made conflicts, climate change, and economic downturns. Forecasting the state of food insecurity is essential to be able to trigger early actions, for example, by humanitarian actors. To measure the actual state of food insecurity, expert and consensus-based approaches and surveys are currently used. Both require substantial manpower, time, and budget. This paper introduces an extreme gradient-boosting machine learning model to forecast monthly transitions in the state of food security in Ethiopia, at a spatial granularity of livelihood zones, and for lead times of one to 12 months, using open-source data. The transition in the state of food security, hereafter referred to as predictand, is represented by the Integrated Food Security Phase Classification Data. From 19 categories of datasets, 130 variables were derived and used as predictors of the transition in the state of food security. The predictors represent changes in climate and land, market, conflict, infrastructure, demographics and livelihood zone characteristics. The most relevant predictors are found to be food security history and surface soil moisture. Overall, the model performs best for forecasting Deteriorations and Improvements in the state of food security compared to the baselines. The proposed method performs (F1 macro score) at least twice as well as the best baseline (a dummy classifier) for a Deterioration. The model performs better when forecasting long-term (7 months; F1 macro average = 0.61) compared to short-term (3 months; F1 macro average = 0.51). Combining machine learning, Integrated Phase Classification (IPC) ratings from monitoring systems, and open data can add value to existing consensus-based forecasting approaches as this combination provides longer lead times and more regular updates. Our approach can also be transferred to other countries as most of the data on the predictors are openly available from global data repositories.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ The Science of The T...arrow_drop_down
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    The Science of The Total Environment
    Article . 2021 . Peer-reviewed
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    The Science of The Total Environment
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    The Science of The Total Environment
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      The Science of The Total Environment
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      The Science of The Total Environment
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    Authors: Valeria D'Ambrosio; Alessandro Sgobbo;

    The paper presents the intermediate results of the design experimentation of a Public Housing development in which the Renewable Energy Community model is an opportunity for energy transition but also for the needs of social inclusion and collaboration, which characterise the complex conditions of contemporary housing. Demonstrating the transcalar and multifunctional effectiveness of RECs incentivises their implementation, especially when a complex demanding framework is confronted with limitedly available resources. Hence, through a systemic approach, simulative methods and impact indicators, the extent of the contribution offered by the REC model was verified not only in terms of decarbonisation and climate neutrality but as an opportunity for eco-social regeneration.

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    Techne
    Article . 2023 . Peer-reviewed
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    Authors: Valeria D'Ambrosio; Alessandro Sgobbo;

    The paper presents the intermediate results of the design experimentation of a Public Housing development in which the Renewable Energy Community model is an opportunity for energy transition but also for the needs of social inclusion and collaboration, which characterise the complex conditions of contemporary housing. Demonstrating the transcalar and multifunctional effectiveness of RECs incentivises their implementation, especially when a complex demanding framework is confronted with limitedly available resources. Hence, through a systemic approach, simulative methods and impact indicators, the extent of the contribution offered by the REC model was verified not only in terms of decarbonisation and climate neutrality but as an opportunity for eco-social regeneration.

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    Techne
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    Authors: Paul Palmay; Cesar Puente; Diego Barzallo; Joan Carles Bruno;

    Currently, the pyrolysis process is an important technology for the final treatment of plastic waste worldwide. For this reason, knowing in detail the chemical process and the thermodynamics that accompany cracking reactions is of utmost importance. The present study aims to determine the thermodynamic parameters of the degradation process of conventional thermoplastics (polystyrene (PS), polyethylene terephthalate (PET), high-density polyethylene (HDPE), polypropylene (PP) and polyvinyl chloride (PVC)) from the study of their chemical kinetics by thermogravimetric analysis (TG). Non-isothermal thermogravimetry was performed at three heating rates from room temperature to 550 °C with an inert nitrogen atmosphere with a flow of 20 mL min−1. Once the TG data is obtained, an analysis is carried out with the isoconversional models of Friedman (FR), Kissinger–Akahira–Sunose (KAS), and Flynn–Wall–Ozawa (FWO) in order to determine the one that best fits the experimental data, and with this, the calculation of the activation energy and the pre-exponential factor is performed. The validation of the model was carried out using the correlation factor, determining that the KAS model is the one that best adjusts for the post-consumer thermoplastic degradation process at the three heating rates. With the use of the kinetic parameters, the variation of the Gibbs free energy is determined in each of the cases, where it is necessary that for structures containing aromatic groups a lower energy is presented, which implies a relative ease of degradation compared to the linear structures.

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    Polymers
    Article . 2021 . Peer-reviewed
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    Polymers
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    PubMed Central
    Other literature type . 2021
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    Polymers
    Article . 2021
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      Polymers
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      Polymers
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      Polymers
      Article . 2021
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    Authors: Paul Palmay; Cesar Puente; Diego Barzallo; Joan Carles Bruno;

    Currently, the pyrolysis process is an important technology for the final treatment of plastic waste worldwide. For this reason, knowing in detail the chemical process and the thermodynamics that accompany cracking reactions is of utmost importance. The present study aims to determine the thermodynamic parameters of the degradation process of conventional thermoplastics (polystyrene (PS), polyethylene terephthalate (PET), high-density polyethylene (HDPE), polypropylene (PP) and polyvinyl chloride (PVC)) from the study of their chemical kinetics by thermogravimetric analysis (TG). Non-isothermal thermogravimetry was performed at three heating rates from room temperature to 550 °C with an inert nitrogen atmosphere with a flow of 20 mL min−1. Once the TG data is obtained, an analysis is carried out with the isoconversional models of Friedman (FR), Kissinger–Akahira–Sunose (KAS), and Flynn–Wall–Ozawa (FWO) in order to determine the one that best fits the experimental data, and with this, the calculation of the activation energy and the pre-exponential factor is performed. The validation of the model was carried out using the correlation factor, determining that the KAS model is the one that best adjusts for the post-consumer thermoplastic degradation process at the three heating rates. With the use of the kinetic parameters, the variation of the Gibbs free energy is determined in each of the cases, where it is necessary that for structures containing aromatic groups a lower energy is presented, which implies a relative ease of degradation compared to the linear structures.

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    Polymers
    Article . 2021 . Peer-reviewed
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    Polymers
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    PubMed Central
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    Polymers
    Article . 2021
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      Polymers
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      Polymers
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      Polymers
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