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In recent years, deregulation in the power generation market worldwide combined with significant variation in fuel prices and a need for flexibility in terms of power augmentation specially during periods of high electricity demand (summer months or noon to 6 PM) has forced electric utilities, cogenerators and independent power producers to explore new power generation enhancement technologies. In the last 5–10 years, inlet fogging approach has shown more promising results to recover lost power output due to increased ambient temperature compared to the other available power enhancement techniques. This paper presents the first systematic study on the effects of both inlet evaporative and overspray fogging on a wide range of combined cycle power plants utilizing gas turbines available from the major gas turbine manufacturers worldwide. A brief discussion on the thermodynamic considerations of inlet and overspray fogging including the effect of droplet dimension is also presented. Based on the analyzed systems, the results show that high pressure inlet fogging influences performance of a combined cycle power plant using an aero-derivative gas turbine differently than with an advanced technology or a traditional gas turbine. Possible reasons for the observed differences are discussed.

Abstract The kinetic characterization of the H 2 / CO system is of interest right now due mainly to its role in sustainable combustion processes. The aim of this paper is to revise and validate a detailed kinetic model of hydrogen and carbon monoxide mixture combustion with particular focus not only on NO x formation but also on interactions with nitrogen species. Model predictions and experimental measurements are discussed and compared across a wide range of operating conditions. This study moves from the detailed analysis of species profiles in syngas oxidation in flow reactor and laminar premixed flames to global combustion properties (ignition delay times and laminar flame speeds) by referring to a large set of literature data. According to recent literature, the validation of the kinetic scheme confirmed there was a need to slightly modify the kinetic parameters of two relevant CO 2 formation reactions ( CO + OH = CO 2 + H and CO + O + M = CO 2 + M ) and of reaction HONO + OH = NO 2 + H 2 O .

Given the significant amount of installed generation-capacity based on wind power, and also due to current economic downturn, the subsidies and incentives that have been widely used by wind-power producers to recover their investment costs have decreased and are even expected to disappear in the near future. In these conditions, wind-power producers need to develop offering strategies to make their investments profitable counting solely on the market. This paper proposes a multi-stage risk-constrained stochastic complementarity model to derive the optimal offering strategy of a wind-power producer that participates in both the day-ahead and the balancing markets. Uncertainties concerning wind-power productions, market prices, demands' bids, and rivals' offers are efficiently modeled using a set of scenarios. The conditional-value-at-risk metric is used to model the profit risk associated with the offering decisions. The proposed model is recast as a tractable mixed-integer linear programming program solvable using available branch-and-cut algorithms. Results of a case study are reported and discussed to show the effectiveness and applicability of the proposed approach.

The effect of external EGR on knock was evaluated using a CFR engine. Combustion pressure was sampled on a time basis. A band pass filter in the time domain was applied to the pressure cycles. Five knock indices were calculated for each combustion cycle. The problem to quantify knock intensity was focused. At this extent, measurements were carried out on standard iso-octane-n-heptane blends in the test conditions used for the determ of the Motor Method Octane Number (MON). Knock intensity was varied acting on compression ratio. For each index, the conditions of absence of knock were determined using motored cycles. The indices were compared and one of them, showing the lowest C.O.V., was selected for further measurements. The effect of EGR on test fuels having different composition was evaluated varying the compression ratio, at fixed ignition timing. In this way, the same level of detonation, obtained in the absence of EGR, was realized with different amounts of external EGR. Percent variation of compression ratio was used to compare the ability of fuels, having different octane number, to tolerate compression ratio increase in presence of EGR. In particular, the tests were carried out on a matrix of twelve fuels with three levels of EGR. The results show that with all tested fuels the percent increase of compression ratio is strongly dependent on EGR.

The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.

AbstractIn this work, the drying step for cathodes based on carbon‐coated LiFePO4 prepared in the temperature range of 60–120 °C has been investigated in detail. The microstructure of the cathode shows a homogeneous distribution of the active material and conductive additive particles independent of the drying temperature. However, the results of impedance spectroscopy and cycling voltammetry are affected by the drying temperature. The solvent evaporation temperature, therefore, affects the polymer binder distribution and its characteristics, which include the polar phase content of the polymer and its affinity with the other components of the cathode. The discharge capacity value after 50 cycles is 120 and 81 mAh g−1 for the samples dried at 80 and 60 °C, respectively, which show the best and worst battery performance, respectively. It was concluded that carbon‐coated LiFePO4 cathodes should be prepared at drying temperatures between 80 and 100 °C for optimized performance.

Thirty four crude extracts of Panamanian plants, from nine species of Celastraceae and Lamiaceae, were assayed for xanthine oxidase (XO) inhibitory activity. The enzymatic activity was estimated by measuring the increase in absorbance at 290 nm due to uric acid formation. Eighty five percent of the crude extracts were found to possess XO inhibitory activity at 50 micrograms/ml and all the extracts of the species from Lamiaceae were active even at 1 micrograms/ml. The ethanol extracts of Hyptis obtusiflora Presl ex Benth. (Lamiaceae) and H. lantanaefolia Poit. (Lamiaceae) exhibited the highest activity with an inhibition of approximately 40% at 1 micrograms/ml.