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Microcystis development in most temperate lakes shows an annual cycle that is mainly triggered by water temperature and includes four stages. This study aims to identify the optimum growth temperature and the temperature thresholds for recruitment and overwintering in Microcystis in Lake Taihu, based on field data and experiments at the cellular and genetic level on Microcystis under a simulated temperature condition. The field investigation showed that the cyanobacterial biomass began to increase at 11-15 °C in spring, reached a peak at 20-30 °C and remained at a low level after the water temperature declined below 6 °C. The simulation experiment found that the recovery of gene expression, photosynthesis and growth in Microcystis cells occurred at 11-14 °C and increased to an appreciable level after the temperature exceeded 20 °C. Microcystis cells stopped growing and maintained low photosynthetic activity and gene expression when the temperature declined to 10 °C or lower. These results suggest that Microcystis in Lake Taihu begin recruitment at 11-14 °C in spring and grow vigorously at 20-30 °C, then overwinter at 10 °C or lower in winter.

Anaerobic digestion of high solids chicken manure was conducted in a batch screening assay. Different mixtures of the fresh manure and anaerobically digested sludge or pit manure, resulting in different total solids levels, were incubated at 35°C. The efficiency of organic matter conversion to methane was found to decrease with increasing organic loads to the digesters. The highest solids at which the digestion was still feasible was around 10% total solids. Methanogenesis took place at free ammonia (NH3) concentrations of up to 250 mg/l. The efficiency of organic nitrogen conversion to ammonia (NH3+NH+4) ranging from 62·6% to as high as 80·3% was achieved in most digestions.

Hot flue gas evaporation technology is an effective strategy for zero liquid discharge of desulfurization wastewater. However, there is a potential risk that heavy metals such as Hg may be released from the wastewater during evaporation, disrupting the original balance of the power plant or even exceeding the Hg emission standard. Wastewater evaporation and Hg release behavior were obtained using a single droplet drying system. At an evaporation temperature of 300 °C, approximately 18.5% of Hg was released in the constant wet-bulb temperature period, and the remaining was released in the following evaporation periods. Furthermore, a fixed-bed experiment, in combination with density functional theory calculations, was used to investigate the possible migration mechanisms of released Hg. The results revealed that high HCl concentration, introduced fly ash, and precipitated evaporation products play a crucial role in the fate of Hg, and 85.3% of Hg finally turned into less harmful particulate-bound Hg. This study provides a new and effective strategy for evaluating the migration process of pollutants in wastewater treatment. Moreover, it will serve as an essential reference for advanced wastewater treatment and heavy metals control technologies in the future.

Land application of food processing wastes has become an acceptable practice because of the nutrient value of the wastes and potential cost savings in their disposal. Spoiled beets and pulp are among the main by‐products generated by the sugar beet (Beta vulgaris L.) processing industry. Farmers commonly land apply these by‐products at rates >224 Mg ha−1 on a fresh weight basis. However, information on nutrient release in soils treated with these by‐products and their subsequent impacts on crop yield is lacking. Field studies were conducted to determine the effects of sugar beet by‐product application on N release and crop yields over two growing seasons. Treatments in the first year were two rates (224 and 448 Mg ha−1 fresh weight) of pulp and spoiled beets and a nonfertilized control. In the second year after by‐product application, the control treatment was fertilized with N fertilizer and an additional treatment was added as a nonfertilized control in buffer areas. Wheat (Triticum aestivum L.) was grown in the year of by‐product application and sugar beet in the subsequent year. By‐product treatments caused a significant reduction in wheat grain yield compared with the control. This was due to a decline in N availability as a result of immobilization. Based on microplots receiving 15N labeled beets, wheat took up <1% of spoiled beet‐N (approximately 4.7 kg ha−1) during the year of by‐product application. In the second cropping year, sugar beet root yields were significantly higher in the fertilized control and by‐product treatments than the nonfertilized control. The lack of significant difference in sugar beet yield between the fertilized control and by‐product treatments was likely due to the greater availability of N in the second year. Labeled 15N data also showed that the sugar beet crop recovered a 17% of sugar beet‐N, an equivalent of 86 kg N ha−1, during the second cropping year. There was no difference in sugar beet root yield, N uptake, or soil N mineralization during the sugar beet cropping season between the pulp and the spoiled beet treatments at comparable rates of application.

Abstract Thermal energy storage (TES) can significantly increase the overall efficiency and operational flexibility of a distributed generation system. A sensible water storage tank is an attractive option for integration in building energy systems due to its low cost and high heat capacity. As such, this paper presents a model for stratified water storage that can be used in building energy simulations and distributed generation simulations. The presented model considers a pressurized water tank with two heat exchangers supplying hot and cold water respectively, where 1-D transient heat balance equations are used to determine the temperature profiles at a given vertical location. The paper computationally investigates the effect of variable flow-rates inside the heat exchangers, the effect of transient heat source, and buoyancy inside the tank induced by location and length of the heat exchangers. The model also considers variation in thermophysical properties and heat loss to the ambient. TES simulation results compare favorably with similar 1-D water storage tank simulations, and the buoyancy model presented agrees with COMSOL 3-D simulations. The analysis shows that when the inlet hot fluid temperature is time dependent, there is a phase lag between the stored water and the hot fluid temperature. Furthermore, it was observed that an increase in flow-rate inside the hot heat exchanger increases the stored water and the cold water outlet temperature; however, the increment in temperature observes diminishing returns with increasing flow-rate of hot fluid. It was also noted that for either heat exchanger, increasing the vertical height of the heat exchanger above a certain value does not significantly increase the cold fluid outlet temperature. Results from the model simulations can assist building designers to determine the size and configurations of a thermal storage tank suited for a given distributed generation system, as well as allowing them to accurately predict the fraction of heat generated by the system that could be stored in the tank at a given time when charging, or the fraction of heating load that could be met by the tank when discharging.

AbstractA simple and low‐cost modification method was developed to improve the power generation performance of inexpensive semicoke electrode in microbial fuel cells (MFCs). After carbonization and activation with water vapor at 800–850 °C, the MFC with the activated coke (modified semicoke) anode produced a maximum power density of 74 W m−3, 17 W m−3, and 681 mW m−2 (normalized to anodic liquid volume, total reactor volume, and projected membrane surface area, respectively), which was 124 % higher than MFCs using a semicoke anode (33 W m−3, 8 W m−3, and 304 mW m−2). When they were used as biocathode materials, activated coke produced a maximum power density of 177 W m−3, 41 W m−3, and 1628 mW m−2 (normalized to cathodic liquid volume, total reactor volume, and projected membrane surface area, respectively), which was 211 % higher than that achieved by MFCs using a semicoke cathode (57 W m−3, 13 W m−3, and 524 mW m−2). A substantial increase was also noted in the conductivity, C/O mass ratio, and specific area for activated coke, which reduced the ohmic resistance, increased biomass density, and promoted electron transfer between bacteria and electrode surface. The activated coke anode also produced a higher Coulombic efficiency and chemical oxygen demand removal rate than the semicoke anode.

The on-going annual increase in global methane (CH4) emissions can be largely attributed to anthropogenic activities. However, as more than half of these emissions are diffuse and possess a concentration less than 3% (v/v), physical-chemical treatments are inefficient as an abatement technology. In this regard, biotechnologies, such as biofiltration using methane-oxidizing bacteria, or methanotrophs, are a cost-effective and efficient means of combating diffuse CH4 emissions. In this review, a number of abiotic factors including temperature, pH, water content, packing material, empty-bed residence time, inlet gas flow rate, CH4 concentration, as well biotic factors, such as biomass development, are reviewed based on empirical findings on CH4 biofiltration studies that have been performed in the last decades.

Abstract Flow-through experiments in the laboratory were conducted to monitor the fate of CO2 using stable carbon isotope (δ13C) techniques in dynamic, pre-equilibrium conditions. Such conditions are typical, for instance in carbon capture storage (CCS), in the initial stages of CO2 injection, near injection well regions of the reservoir. For this purpose, a reactive percolation bench (ICARE 4) was used, injecting a CO2-saturated brine at supercritical conditions (pCO2 = 84 bar, T = 60 °C) through quartzitic limestone at an average flow rate of 2 × 10− 9 m3 s− 1. Calcium (Ca2 +) and dissolved inorganic carbon (DIC) concentration data and pH were used to aid analytical interpretations. During CO2 injection, δ13CDIC values decreased from about − 11‰ to those of the injected CO2 (− 29.3‰), indicating CO2 sourced carbon dominance over a carbonate sourced one in the system. Simultaneously DIC and Ca2 + concentrations increased from 1 mmol L− 1 to a maximum of 71 mmol L− 1 and 31 mmol L− 1, respectively. Isotope and mass balances were used to quantify the amount of DIC originating from either the injected CO2 or carbonates. At the end of the experiments, between 70 and 98% of the total DIC originated from CO2 dissolution, the remaining amount is attributed to carbonate dissolution. Furthermore, the total amount of injected CCO2 trapped as DIC ranged between 9 and 17% and between 83 and 91% was in free phase. The state of carbonate equilibrium of the host fluid, under the high pressure–temperature conditions after CO2 injection was identified, verifying pre-equilibrium conditions. Results confirm observations made in reported field data. This emphasises that the combination of CO2 monitoring, the development of a thorough understanding of carbonate equilibrium, as well as the quantification of CO2-trapping, is essential for a solid assessment of reservoir performance and safety considerations during CO2 injection. These are equally important for understanding water–rock–CO2 dynamics in natural subsurface environments.

Microbial fuel cells (MFCs) can remove and recover metals in wastewater; however, there are relatively few studies of metal removal from soil by MFCs. In this study, we developed a three-chamber soil MFC consisting of an anode, contaminated soil, and cathode chamber to remove heavy metals from soil. The performance of the soil MFC was investigated by assessing the relationships among current, voltage, and Cu migration, and reduction. The developed soil MFC successfully reduced and removed Cu, and the Cu removal efficiency in the cathode surpassed 90% after only 7 days of operation. External resistance had a remarkable effect on the performance of the soil MFC which was depended on cathodic polarization. The pH in the cathode also depended on the external resistance. Lower external resistance were associated with lower pH values, higher Cu removal efficiencies, and greater amounts removed in the cathode. Based on sequential fractionation, the acid-extractable and reducible fractions were the main fractions that migrated within the three-chamber soil MFC. Enhancing the voltage output in the three-chamber soil MFC by increasing the external resistance promoted Cu migration, enriched Cu near the cathode, and facilitated Cu removal. Therefore, the developed three-chamber soil MFC not only supports heavy metal migration from soil towards the cathode, but can also realize reduction of heavy metals in the cathode by adjusting the current or voltage generated by the soil MFC.