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Hot water heat stores with stratification are a common technology used in solar energy systems and reuse of waste heat. Adding a PCM module at the top of the water tank would give the system higher storage density, and compensate heat loss in the top layer. The work presented here includes experimental results and numerical simulation of the system using an explicit finite-difference method. Experiments and simulations were carried out using different cylindrical PCM modules. With only 1/16 of the volume of the store being PCM, 3/16 of water at the top of the store was held warm for 50% to 200% longer and the average energy density was increased by 20% to 45%. Furthermore, these 3/16 of water were reheated by the heat from the module after being cooled down in only 20 min.

Biodegradation rates of benzoate and related aromatic compounds, 3-nitrobenzoate, 4-chlorobenzoate, 4-chlorophenol, and 2,4-dichlorophenol by unexposed (unacclimated) and long-term exposed (acclimated) biomass were quantified using a modified fed-batch technique. The acclimated biomass was taken after approximately 1-year of operation from three lab-scale sequencing batch reactors (SBR). These reactors were operated under various cycling electron acceptor conditions with a continuous feed of a synthetic wastewater containing biogenic and nonbiogenic chemicals including benzoate, 3-nitrobenzoate, and 4-chlorophenol, but not 4-chlorobenzoate or 2,4-dichlorophenol. The unexposed biomass was taken from a full-scale wastewater treatment plant, which constituted one of the original sources of inoculum for the lab-scale SBRs. The acclimated biomass manifested high removal rates of benzoate and related aromatic compounds with additional removal of structurally similar chemicals (4-chlorobenzoate and 2,4-dichlorophenol). The unacclimated biomass showed no removal of 3-nitrobenzoate, 4-chlorobenzoate or 2,4-dichlorophenol. Addition of biogenic substrates reduced the degradation of most aromatic compounds tested, but it enhanced 2,4-dichlorophenol removal. Biodegradation rates of each aromatic compound with the biomass from the anoxic/aerobic SBR were further determined under anaerobic (absence of aeration and NO3-), anoxic (no aeration, but with surplus NO3-), standard oxygen (DO > 0.2 mg/L), and elevated oxygen (DO > 25 mg/L) conditions. The removal rate of both benzoate and 3-nitrobenzoate decreased under anaerobic condition but not under the anoxic condition; 4-chlorophenol biodegradation, on the other hand, was reduced significantly under both anoxic and anaerobic conditions. The removal rates of aromatic compounds, particularly those of 3-nitrobenzoate and 2,4-dichlorophenol, increased significantly under elevated dissolved oxygen conditions. Our results demonstrated that when the biochemical conditions shifted from oxygen-respiration to nitrate respiration, to anaerobiosis, the biodegradation rates of test aromatic compounds decreased or ceased.

The Indian Ocean Experiment (INDOEX) was an international, multiplatform field campaign to measure long-range transport of air pollution from South and Southeast Asia toward the Indian Ocean during the dry monsoon season in January to March 1999. Surprisingly high pollution levels were observed over the entire northern Indian Ocean toward the Intertropical Convergence Zone at about 6°S. We show that agricultural burning and especially biofuel use enhance carbon monoxide concentrations. Fossil fuel combustion and biomass burning cause a high aerosol loading. The growing pollution in this region gives rise to extensive air quality degradation with local, regional, and global implications, including a reduction of the oxidizing power of the atmosphere.

Roundtables for sustainable beef have evolved in national contexts as well as at the global level as a multi-stakeholder process to address sustainability concerns in the cattle sector. However, due to their relatively recent inception, the literature on the beef roundtables is extremely limited and very little scholarly work has traced their process or impact. We used semi-structured interviews with key informants to examine the governance, actions, and potential impacts of the roundtables for sustainable beef, and identified opportunities and challenges for achieving greater sustainability impact. We found that the beef roundtables are in different stages of development and implementation and that they have diverse approaches based on their geographic contexts. However, they have universally adopted a model of sector-wide continuous improvement, in contrast to roundtables for other commodities, which have in many cases adopted formal certification programs. Activities by the roundtables for sustainable beef have variously included working towards definitions of sustainable beef; setting sustainability principles and criteria; and creating working groups to address specific aspects of sustainability (e.g., verification, deforestation). Our interviews identified opportunities to expand the roundtables’ roles, activities, and sustainability impacts. This study provides a benchmark of the roundtables’ efforts to date, and generates hypotheses and ideas for how they could evolve in the future.

Worldwide, 98% of total electricity is currently produced by thermoelectric power and hydropower. Climate change is expected to directly impact electricity supply, in terms of both water availability for hydropower generation and cooling water usage for thermoelectric power. Improved understanding of how climate change may impact the availability and temperature of water resources is therefore of major importance. Here we use a multi-model ensemble to show the potential impacts of climate change on global hydropower and cooling water discharge potential. For the first time, combined projections of streamflow and water temperature were produced with three global hydrological models (GHMs) to account for uncertainties in the structure and parametrization of these GHMs in both water availability and water temperature. The GHMs were forced with bias-corrected output of five general circulation models (GCMs) for both the lowest and highest representative concentration pathways (RCP2.6 and RCP8.5). The ensemble projections of streamflow and water temperature were then used to quantify impacts on gross hydropower potential and cooling water discharge capacity of rivers worldwide. We show that global gross hydropower potential is expected to increase between +2.4% (GCM-GHM ensemble mean for RCP 2.6) and +6.3% (RCP 8.5) for the 2080s compared to 1971–2000. The strongest increases in hydropower potential are expected for Central Africa, India, central Asia and the northern high-latitudes, with 18–33% of the world population living in these areas by the 2080s. Global mean cooling water discharge capacity is projected to decrease by 4.5-15% (2080s). The largest reductions are found for the United States, Europe, eastern Asia, and southern parts of South America, Africa and Australia, where strong water temperature increases are projected combined with reductions in mean annual streamflow. These regions are expected to affect 11–14% (for RCP2.6 and the shared socio-economic pathway (SSP)1, SSP2, SSP4) and 41–51% (RCP8.5–SSP3, SSP5) of the world population by the 2080s.

The Authors tested a complete new system for recovering wood fuel from the termination of depleted orchards. This operation can generate between 25 and 80 fresh t ha?¹, that can be directed to the growing bioenergy sector. The new system is based on highly-mobile low-investment general-purpose equipment, which allows containing operational cost and speeding relocation between work sites. The new residue collection system is quite flexible, and achieves cost-effective recovery on relatively small fields, often smaller than 1 ha. Under the conditions of the study, trees are cut, chipped and delivered at a cost between 35 and 40 EUR t?¹ (40% water mass fraction), provided that fields are within a 20 km distance from the biomass plant. Use of a standard drum chipper results in a better product quality than if a grinders is used, as is the case for conventional orchard removal operations. Feeding the chipper with a separate loader allows a significant cost reduction, provided that the field offers at least 25 t of fresh wood. In the future, use of remote controls and electronic tethers may allow a further cost reduction, which is estimated at 15%.

Aim of the present paper is to investigate and compare the performance of three different possible membrane condenser configurations in terms of amount of recovered liquid water and energy consumption. Membrane condenser is an innovative unit operation utilized for the recovery of evaporated waste water from industrial gases. In the first proposed configuration, the fed waste gas is cooled by cooling water before entering the membrane module; in the second configuration the cooling is obtained inside the membrane module through a cold sweeping gas; the third configuration is in between the two previous ones: the fed waste gas is first partially cooled via an external medium and then a sweeping gas is used for the final cooling of the stream. The achieved results indicate that configuration 2 has the lowest energy consumption, and configuration 3 allows achieving the highest water recovery whereas its energy consumption is in between configuration 1 and 2.

Bioenergy crops are well known for their ability to reduce greenhouse gas emissions and increase the soil carbon stock. Although such crops are often held to be in competition with food crops and thus raise the question of current and future food security, at the same time mitigation measures are required to tackle climate change and sustain local farming communities and crop production. However, in some cases the actions envisaged for specific pedo-climatic conditions are not always economically sustainable by farmers. In this frame, energy crops with high environmental adaptability and yields, such as giant reed (Arundo donax L.), may represent an opportunity to improve farm incomes, making marginal areas not suitable for food production once again productive. In so doing, three of the 17 Sustainable Development Goals (SDGs) of the United Nations would be met, namely SDG 2 on food security and sustainable agriculture, SDG 7 on reliable, sustainable and modern energy, and SDG 13 on action to combat climate change and its impacts. In this work, the response of giant reed in the marginal areas of an agricultural district of southern Italy (Destra Sele) and expected farm incomes under climate change (2021-2050) are evaluated. The normalized water productivity index of giant reed was determined (WP; 30.1gm-2) by means of a SWAP agro-hydrological model, calibrated and validated on two years of a long-term field experiment. The model was used to estimate giant reed response (biomass yield) in marginal areas under climate change, and economic evaluation was performed to determine expected farm incomes (woodchips and chopped forage). The results show that woodchip production represents the most profitable option for farmers, yielding a gross margin 50% lower than ordinary high-input maize cultivation across the study area.