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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jun He; Ke Wang; Jiangang Li;

    Pyro-breaker, a fast-responding, highly reliable and explosive-driven circuit breaker, is utilized in several Quench Protection Systems (QPS). The commutation process and its parameters are the main technical considerations in the process of designing a new pyro-breaker. The commutation parameters, such as the commutation time and the current change rate, are not only determined by the electrical parameters of the commutation circuit but also the arc behavior during the operation. The arc behavior is greatly affected by the structure and the driving mechanism of the Commutation Section (CS) in the pyro-breaker. The arc model was developed decades ago and the black-box arc model is considered a valid method to study arc behavior. In this paper, the Schavemaker black-box arc model, an improved Mayr-type arc model, is applied to study the commutation process of a newly designed pyro-breaker. Unlike normal circuit breakers, the arc discussed in this paper is discharged in deionized water. A parameter selection method is proposed. The practicability of the method is verified by numerical calculation in Power Systems Computer Aided Design (PSCAD) and experimentally.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2021 . Peer-reviewed
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    Energies
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    Energies
    Article . 2021
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2021 . Peer-reviewed
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      Energies
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      Energies
      Article . 2021
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jun He; Ke Wang; Jiangang Li;

    Pyro-breaker, a fast-responding, highly reliable and explosive-driven circuit breaker, is utilized in several Quench Protection Systems (QPS). The commutation process and its parameters are the main technical considerations in the process of designing a new pyro-breaker. The commutation parameters, such as the commutation time and the current change rate, are not only determined by the electrical parameters of the commutation circuit but also the arc behavior during the operation. The arc behavior is greatly affected by the structure and the driving mechanism of the Commutation Section (CS) in the pyro-breaker. The arc model was developed decades ago and the black-box arc model is considered a valid method to study arc behavior. In this paper, the Schavemaker black-box arc model, an improved Mayr-type arc model, is applied to study the commutation process of a newly designed pyro-breaker. Unlike normal circuit breakers, the arc discussed in this paper is discharged in deionized water. A parameter selection method is proposed. The practicability of the method is verified by numerical calculation in Power Systems Computer Aided Design (PSCAD) and experimentally.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2021 . Peer-reviewed
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    Energies
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    Energies
    Article . 2021
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2021 . Peer-reviewed
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      Energies
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      Energies
      Article . 2021
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Ting Chen; Zhengming Yang; Yutian Luo; Wei Lin; +3 Authors

    In order to evaluate the displacement effect of four kinds of injection media in tight oil sandstone, water, active water, CO2, N2 flooding experiments were carried out in laboratory. Online Nuclear Magnetic Resonance (NMR) spectrometers combine the advantages of NMR technology and core displacement experiments. In the displacement experiment, NMR data of different injection volumes were obtained and magnetic resonance imaging (MRI) was carried out. The results showed that micro and sub-micropores provided 62–97% of the produced crude oil. The enhanced oil recovery ratio of active water flooding was higher than that of conventional water flooding up to 10%. The recovery ratio of gas flooding in micro and sub-micropores was 60–70% higher than that of water flooding. The recovery ratio of CO2 flooding was 10% higher than that of N2 flooding. The remaining oil was mainly distributed in pores larger than 0.1 μm. Under the same permeability level, the remaining oil saturation of cores after gas flooding was 10–25% lower than water flooding. From MRI images, the displacement effects from good to bad were as follows: CO2 flooding, N2 flooding, active water flooding, and conventional water flooding.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2018 . Peer-reviewed
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    Energies
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    Energies
    Article . 2018
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      Article . 2018 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Ting Chen; Zhengming Yang; Yutian Luo; Wei Lin; +3 Authors

    In order to evaluate the displacement effect of four kinds of injection media in tight oil sandstone, water, active water, CO2, N2 flooding experiments were carried out in laboratory. Online Nuclear Magnetic Resonance (NMR) spectrometers combine the advantages of NMR technology and core displacement experiments. In the displacement experiment, NMR data of different injection volumes were obtained and magnetic resonance imaging (MRI) was carried out. The results showed that micro and sub-micropores provided 62–97% of the produced crude oil. The enhanced oil recovery ratio of active water flooding was higher than that of conventional water flooding up to 10%. The recovery ratio of gas flooding in micro and sub-micropores was 60–70% higher than that of water flooding. The recovery ratio of CO2 flooding was 10% higher than that of N2 flooding. The remaining oil was mainly distributed in pores larger than 0.1 μm. Under the same permeability level, the remaining oil saturation of cores after gas flooding was 10–25% lower than water flooding. From MRI images, the displacement effects from good to bad were as follows: CO2 flooding, N2 flooding, active water flooding, and conventional water flooding.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
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    Authors: Bo Gao; Hongmei Shao; Jiyong Li; Haoyuan Jiang; +7 Authors

    Pore network modeling based on digital rock is employed to evaluate the mobility of shale oil in Qingshankou Formation, Songliao Basin, China. Computerized tomography technology is adopted in this work to reconstruct the digital rock of shale core. The pore network model is generated based on the computerized tomography data. We simulate the dynamics of fluid flow in a pore network model to evaluate the mobility of fluid in shale formation. The results show that the relative permeability of oil phase increases slowly in the initial stage of the displacement process, which is mainly caused by the poor continuity of the oil phase. In the later stages, with the increase in the oil phase continuity, the range of relative permeability increases. With the increase of organic matter content, the permeability of the water phase remains unchanged at low water saturation, but gradually increases at high water saturation. At the same time, it can be seen that, with the increase in organic matter content, the isosmotic point of the oil–water phase permeability shifts to the left, indicating that the wettability to water phase gradually weakens.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2021 . Peer-reviewed
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    Energies
    Article . 2021
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      Energies
      Article . 2021 . Peer-reviewed
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      Energies
      Article . 2021
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    Authors: Bo Gao; Hongmei Shao; Jiyong Li; Haoyuan Jiang; +7 Authors

    Pore network modeling based on digital rock is employed to evaluate the mobility of shale oil in Qingshankou Formation, Songliao Basin, China. Computerized tomography technology is adopted in this work to reconstruct the digital rock of shale core. The pore network model is generated based on the computerized tomography data. We simulate the dynamics of fluid flow in a pore network model to evaluate the mobility of fluid in shale formation. The results show that the relative permeability of oil phase increases slowly in the initial stage of the displacement process, which is mainly caused by the poor continuity of the oil phase. In the later stages, with the increase in the oil phase continuity, the range of relative permeability increases. With the increase of organic matter content, the permeability of the water phase remains unchanged at low water saturation, but gradually increases at high water saturation. At the same time, it can be seen that, with the increase in organic matter content, the isosmotic point of the oil–water phase permeability shifts to the left, indicating that the wettability to water phase gradually weakens.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2021 . Peer-reviewed
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    Energies
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    Energies
    Article . 2021
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      Energies
      Article . 2021 . Peer-reviewed
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      Energies
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      Energies
      Article . 2021
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    Authors: Shengpeng Xia; Anqing Zheng; Kun Zhao; Zengli Zhao; +1 Authors

    To reveal the effect of torrefaction pretreatment on pyrolysis and gasification reactivity of biomass, corn cob was first subjected to torrefaction pretreatment in a fixed-bed reactor at various reaction temperatures. The pyrolysis reactivity, kinetics, and gasification reactivity of torrefied corn cob were systematically assessed by various methods, proving that torrefaction pretreatment has a substantial influence on the physicochemical properties of corn cobs. The O/C and H/C molar ratios of corn cobs considerably drop with the increasing torrefaction temperature, and their higher heat-ing value (HHV) and energy density rise as well. It is found that torrefaction improves the pyrolysis reactivity of corn cobs because hemicellulose degradation is more severe than cellulose degradation during torrefaction, resulting in an increase in the percentage of cellulose in torrefied corn cobs. However, the severe depolymerization, polycondensation, and carbonization reaction during torre-faction of corn cobs at 280–300 °C can lead to a significant decline in the pyrolysis reactivity of corn cobs. Torrefaction pretreatment increases the pyrolysis activation energy of corn cobs, in addition to decreasing the char gasification reactivity of corn cob. The average char gasification reactivity of corn cobs drops when torrefaction severity increases. The passivation of active sites on the char surface may cause condensation and carbonation reactions of corn cobs during torrefaction. These findings provide new sights into the reasonable design of efficient torrefaction methods for appli-cation prior to pyrolysis and gasification of biomass.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2022 . Peer-reviewed
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    Energies
    Article . 2022
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      Energies
      Article . 2022 . Peer-reviewed
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      Energies
      Article . 2022
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    Authors: Shengpeng Xia; Anqing Zheng; Kun Zhao; Zengli Zhao; +1 Authors

    To reveal the effect of torrefaction pretreatment on pyrolysis and gasification reactivity of biomass, corn cob was first subjected to torrefaction pretreatment in a fixed-bed reactor at various reaction temperatures. The pyrolysis reactivity, kinetics, and gasification reactivity of torrefied corn cob were systematically assessed by various methods, proving that torrefaction pretreatment has a substantial influence on the physicochemical properties of corn cobs. The O/C and H/C molar ratios of corn cobs considerably drop with the increasing torrefaction temperature, and their higher heat-ing value (HHV) and energy density rise as well. It is found that torrefaction improves the pyrolysis reactivity of corn cobs because hemicellulose degradation is more severe than cellulose degradation during torrefaction, resulting in an increase in the percentage of cellulose in torrefied corn cobs. However, the severe depolymerization, polycondensation, and carbonization reaction during torre-faction of corn cobs at 280–300 °C can lead to a significant decline in the pyrolysis reactivity of corn cobs. Torrefaction pretreatment increases the pyrolysis activation energy of corn cobs, in addition to decreasing the char gasification reactivity of corn cob. The average char gasification reactivity of corn cobs drops when torrefaction severity increases. The passivation of active sites on the char surface may cause condensation and carbonation reactions of corn cobs during torrefaction. These findings provide new sights into the reasonable design of efficient torrefaction methods for appli-cation prior to pyrolysis and gasification of biomass.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2022 . Peer-reviewed
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    Energies
    Article . 2022
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      Energies
      Article . 2022 . Peer-reviewed
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    Authors: Jian Wang; Peng Li; Weizheng Bai; Jun Lu; +3 Authors

    With the development of salt cavern gas storage construction technology, the construction of large-scale gas storage salt caverns using sediment voids is expected to solve the problem of low effective volume formation rate and poor construction economy of high-impurity salt mines. There are few studies on the long-term operation mechanical behavior of salt cavern gas storage under the influence of sediment accumulation currently. This paper studies the influence of sediment accumulation height, particle gradation, and operating pressure on the stability of salt caverns by constructing a coupling model of sediment particle discontinuous medium and surrounding rock continuous medium. The continuous-discontinuous coupling algorithm is suitable for analyzing the influence of particle accumulation height and particle gradation on the creep shrinkage of salt caverns. The increase of sediment accumulation height slows down the creep shrinkage of the bottom of the salt cavern, strengthens the restraining effect on the surrounding rock of the cavern, and moves the position of the maximum displacement of the surrounding rock to the upper part of the cavern; the sediment particle gradation has little effect on the cavern volume shrinkage rate, and the greater the coarse particle content, the smaller the cavern volume shrinkage rate; the greater the operating pressure, the more conducive to maintaining the stability of the cavern, slowing down the upward movement of the sediment body and increasing the gas storage space in the upper part of the cavern. This research results can provide a reference for evaluating the long-term operation stability of sediment-type high-impurity salt cavern gas storage.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ https://doi.org/10.2...arrow_drop_down
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    https://doi.org/10.20944/prepr...
    Article . 2024 . Peer-reviewed
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    Energies
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    Authors: Jian Wang; Peng Li; Weizheng Bai; Jun Lu; +3 Authors

    With the development of salt cavern gas storage construction technology, the construction of large-scale gas storage salt caverns using sediment voids is expected to solve the problem of low effective volume formation rate and poor construction economy of high-impurity salt mines. There are few studies on the long-term operation mechanical behavior of salt cavern gas storage under the influence of sediment accumulation currently. This paper studies the influence of sediment accumulation height, particle gradation, and operating pressure on the stability of salt caverns by constructing a coupling model of sediment particle discontinuous medium and surrounding rock continuous medium. The continuous-discontinuous coupling algorithm is suitable for analyzing the influence of particle accumulation height and particle gradation on the creep shrinkage of salt caverns. The increase of sediment accumulation height slows down the creep shrinkage of the bottom of the salt cavern, strengthens the restraining effect on the surrounding rock of the cavern, and moves the position of the maximum displacement of the surrounding rock to the upper part of the cavern; the sediment particle gradation has little effect on the cavern volume shrinkage rate, and the greater the coarse particle content, the smaller the cavern volume shrinkage rate; the greater the operating pressure, the more conducive to maintaining the stability of the cavern, slowing down the upward movement of the sediment body and increasing the gas storage space in the upper part of the cavern. This research results can provide a reference for evaluating the long-term operation stability of sediment-type high-impurity salt cavern gas storage.

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    Energies
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    Authors: Haobo Chen; Shangyu Liu; Yaoqiu Kuang; Jie Shu; +1 Authors

    Electricity consumption is closely linked to economic growth, social development, and carbon emissions. In order to fill the gap of previous studies on the decomposition of electricity consumption drivers that have not adequately considered carbon emission constraint, this study constructs the Kaya extended model of electricity consumption and analyzes the effects of drivers in industrial and residential sectors using the Logarithmic Mean Divisia Index (LMDI) method, and empirically explores the temporal and spatial differences in electricity consumption. Results show that: (1) During 2005–2021, the total final electricity consumption growth in Guangdong was much higher than that in Yunnan, but the average annual growth rate in Guangdong was lower, and the largest growth in both provinces was in the industrial sector. (2) The labor productivity level effect is the primary driver that increases total final electricity consumption (Guangdong: 78.5%, Yunnan: 87.1%), and the industrial carbon emission intensity effect is the primary driver that decreases total final electricity consumption (Guangdong: −75.3%, Yunnan: −72.3%). (3) The year-to-year effect of each driver by subsector is overall positively correlated with the year-to-year change in the corresponding driver, and declining carbon emission intensity is a major factor in reducing electricity consumption. (4) The difference in each effect between Guangdong and Yunnan is mainly determined by a change in the corresponding driver and subsectoral electricity consumption. Policy implications are put forward to promote energy conservation and the realization of the carbon neutrality goal.

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    Energies
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    Energies
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    Authors: Haobo Chen; Shangyu Liu; Yaoqiu Kuang; Jie Shu; +1 Authors

    Electricity consumption is closely linked to economic growth, social development, and carbon emissions. In order to fill the gap of previous studies on the decomposition of electricity consumption drivers that have not adequately considered carbon emission constraint, this study constructs the Kaya extended model of electricity consumption and analyzes the effects of drivers in industrial and residential sectors using the Logarithmic Mean Divisia Index (LMDI) method, and empirically explores the temporal and spatial differences in electricity consumption. Results show that: (1) During 2005–2021, the total final electricity consumption growth in Guangdong was much higher than that in Yunnan, but the average annual growth rate in Guangdong was lower, and the largest growth in both provinces was in the industrial sector. (2) The labor productivity level effect is the primary driver that increases total final electricity consumption (Guangdong: 78.5%, Yunnan: 87.1%), and the industrial carbon emission intensity effect is the primary driver that decreases total final electricity consumption (Guangdong: −75.3%, Yunnan: −72.3%). (3) The year-to-year effect of each driver by subsector is overall positively correlated with the year-to-year change in the corresponding driver, and declining carbon emission intensity is a major factor in reducing electricity consumption. (4) The difference in each effect between Guangdong and Yunnan is mainly determined by a change in the corresponding driver and subsectoral electricity consumption. Policy implications are put forward to promote energy conservation and the realization of the carbon neutrality goal.

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    Energies
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    Authors: Yong Li; Jue Yang; Wei Long Liu; Cheng Lin Liao;

    The lithium-ion battery is a complicated non-linear system with multi electrochemical processes including mass and charge conservations as well as electrochemical kinetics. The calculation process of the electrochemical model depends on an in-depth understanding of the physicochemical characteristics and parameters, which can be costly and time-consuming. We investigated the electrochemical modeling, reduction, and identification methods of the lithium-ion battery from the electrode-level to the system-level. A reduced 9th order linear model was proposed using electrode-level physicochemical modeling and the cell-level mathematical reduction method. The data-driven predictor-based subspace identification algorithm was presented for the estimation of lithium-ion battery model in the system-level. The effectiveness of the proposed modeling and identification methods was validated in an experimental study based on LiFePO4 cells. The accuracy and dynamic characteristics of the identified model were found to be much more likely related to the operating State of Charge (SOC) range. Experimental results showed that the proposed methods perform well with high precision and good robustness in the SOC range of 90% to 10%, and the tracking error increases significantly within higher (100–90%) or lower (10–0%) SOC ranges. Moreover, to achieve an optimal balance between high-precision and low complexity, statistical analysis revealed that the 6th, 3rd, and 5th order battery model is the optimal choice in the SOC range of 90% to 100%, 90% to 10%, and 10% to 0%, respectively.

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    Energies
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    Article . 2020
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      Energies
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    Authors: Yong Li; Jue Yang; Wei Long Liu; Cheng Lin Liao;

    The lithium-ion battery is a complicated non-linear system with multi electrochemical processes including mass and charge conservations as well as electrochemical kinetics. The calculation process of the electrochemical model depends on an in-depth understanding of the physicochemical characteristics and parameters, which can be costly and time-consuming. We investigated the electrochemical modeling, reduction, and identification methods of the lithium-ion battery from the electrode-level to the system-level. A reduced 9th order linear model was proposed using electrode-level physicochemical modeling and the cell-level mathematical reduction method. The data-driven predictor-based subspace identification algorithm was presented for the estimation of lithium-ion battery model in the system-level. The effectiveness of the proposed modeling and identification methods was validated in an experimental study based on LiFePO4 cells. The accuracy and dynamic characteristics of the identified model were found to be much more likely related to the operating State of Charge (SOC) range. Experimental results showed that the proposed methods perform well with high precision and good robustness in the SOC range of 90% to 10%, and the tracking error increases significantly within higher (100–90%) or lower (10–0%) SOC ranges. Moreover, to achieve an optimal balance between high-precision and low complexity, statistical analysis revealed that the 6th, 3rd, and 5th order battery model is the optimal choice in the SOC range of 90% to 100%, 90% to 10%, and 10% to 0%, respectively.

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    Energies
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    Authors: Donghuan Han; Wei Xiong; Tongwen Jiang; Shusheng Gao; +4 Authors

    Although improving the recovery of water-invaded gas reservoirs has been extensively studied in the natural gas industry, the nature of the efficiency of water-invaded gas recovery remains uncertain. Low-field nuclear magnetic resonance (NMR) can be used to clearly identify changes in water saturation in the core during high-pressure water-invasion gas. Here, we provide four types of water-invasion gas experiments (spontaneous imbibition, atmospheric pressure, high-pressure approximate equilibrium, and depletion development water-invasion gas) to reveal the impact of the water-invasion gas efficiency on the recovery of water-invasion gas reservoirs. NMR suggested that imbibition mainly occurs in medium to large pores and that residual gas remains mainly in large pores. The amount of gas driven out from the large pores by imbibition was much greater than that driven out from the small pores. Our findings indicate that the initial gas saturation, contact surface, and permeability are the main factors controlling the residual gas saturation, suggesting that a reasonable initial water saturation should be established before the water-invasion gas experiments. Additionally, the water-invasion gas efficiency at high pressures can be more reliably obtained than that at normal pressures. After the high-pressure approximate equilibrium water invasion for gas displacement, a large amount of residual gas remains in the relatively larger pores of the core, with a residual gas saturation of 42%. In contrast to conventional experiments, the residual gas saturation and water displacement efficiency of the high-pressure approximate equilibrium water invasion for gas displacement did not exhibit a favorable linear relationship with the permeability. The residual gas saturation ranged from 34 to 43% (avg. 38%), while the water displacement efficiency ranged from 32 to 45% (avg. 40%) in the high-pressure approximate equilibrium water invasion for gas displacement. The residual gas saturation in the depletion development water-invasion gas experiment was 26–40% (average: 33%), with an efficiency ranging from 45 to 50% (average: 48%), indicating that the depletion development experiment is closer to the actual development process of gas reservoirs. Our findings provide novel insights into water-invasion gas efficiency, providing robust estimates of the recovery of water-invasion gas reservoirs.

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    Energies
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    Authors: Donghuan Han; Wei Xiong; Tongwen Jiang; Shusheng Gao; +4 Authors

    Although improving the recovery of water-invaded gas reservoirs has been extensively studied in the natural gas industry, the nature of the efficiency of water-invaded gas recovery remains uncertain. Low-field nuclear magnetic resonance (NMR) can be used to clearly identify changes in water saturation in the core during high-pressure water-invasion gas. Here, we provide four types of water-invasion gas experiments (spontaneous imbibition, atmospheric pressure, high-pressure approximate equilibrium, and depletion development water-invasion gas) to reveal the impact of the water-invasion gas efficiency on the recovery of water-invasion gas reservoirs. NMR suggested that imbibition mainly occurs in medium to large pores and that residual gas remains mainly in large pores. The amount of gas driven out from the large pores by imbibition was much greater than that driven out from the small pores. Our findings indicate that the initial gas saturation, contact surface, and permeability are the main factors controlling the residual gas saturation, suggesting that a reasonable initial water saturation should be established before the water-invasion gas experiments. Additionally, the water-invasion gas efficiency at high pressures can be more reliably obtained than that at normal pressures. After the high-pressure approximate equilibrium water invasion for gas displacement, a large amount of residual gas remains in the relatively larger pores of the core, with a residual gas saturation of 42%. In contrast to conventional experiments, the residual gas saturation and water displacement efficiency of the high-pressure approximate equilibrium water invasion for gas displacement did not exhibit a favorable linear relationship with the permeability. The residual gas saturation ranged from 34 to 43% (avg. 38%), while the water displacement efficiency ranged from 32 to 45% (avg. 40%) in the high-pressure approximate equilibrium water invasion for gas displacement. The residual gas saturation in the depletion development water-invasion gas experiment was 26–40% (average: 33%), with an efficiency ranging from 45 to 50% (average: 48%), indicating that the depletion development experiment is closer to the actual development process of gas reservoirs. Our findings provide novel insights into water-invasion gas efficiency, providing robust estimates of the recovery of water-invasion gas reservoirs.

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    Energies
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    Authors: Nengxiong Xu; Cheng Cheng; Xiao Li; Bo Zheng;

    Dilation behavior is of great importance for reasonable modeling of the stability of the host rock of the repository for high-level radioactive waste disposal. It is a suitable method for carrying out direct shear experiments to analyze the dilation behavior of rock with well understood physical meanings. Based on a series of direct shear experiments on granite samples from the Alxa candidate area under different normal stresses, the shear stress‒shear strain and shear stress‒normal strain relations have been studied in detail. Five typical stages have been divided associated with the fracturing process and deformation behaviors of the granite samples during the experimental process, and the method to determine the typical stress thresholds has been proposed. It has also been found that the increasing normal stress may reduce the maximum dilation angle, and when the normal stress is relatively lower, the negative dilation angle may occur during the post-peak stage. According to the data collected from the direct shear tests, an empirical model of the mobilized dilation angle dependent on normal stress and plastic shear strain is proposed. This mobilized dilation angle has clear physical meanings and can be used in plastic constitutive models of the host rock of the repository, and this analysis can also be put forward to other types of geomechanical problems, including the deformation behaviors related to landslide, earthquake, and so on.

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    Article . 2019 . Peer-reviewed
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    Authors: Nengxiong Xu; Cheng Cheng; Xiao Li; Bo Zheng;

    Dilation behavior is of great importance for reasonable modeling of the stability of the host rock of the repository for high-level radioactive waste disposal. It is a suitable method for carrying out direct shear experiments to analyze the dilation behavior of rock with well understood physical meanings. Based on a series of direct shear experiments on granite samples from the Alxa candidate area under different normal stresses, the shear stress‒shear strain and shear stress‒normal strain relations have been studied in detail. Five typical stages have been divided associated with the fracturing process and deformation behaviors of the granite samples during the experimental process, and the method to determine the typical stress thresholds has been proposed. It has also been found that the increasing normal stress may reduce the maximum dilation angle, and when the normal stress is relatively lower, the negative dilation angle may occur during the post-peak stage. According to the data collected from the direct shear tests, an empirical model of the mobilized dilation angle dependent on normal stress and plastic shear strain is proposed. This mobilized dilation angle has clear physical meanings and can be used in plastic constitutive models of the host rock of the repository, and this analysis can also be put forward to other types of geomechanical problems, including the deformation behaviors related to landslide, earthquake, and so on.

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    Authors: Yong Shi; Anda Tang; Tongsheng Yao;

    In China, environmental pollution responsibilities are divided according to administrative regions. However, because of the strong externality of environmental pollution, the movement of environmental pollution undoubtedly increases the complexity of pollution governance. To divide the responsibility of environmental pollution governance in each province, we effectively quantify the unequal relationship between environmental pollution costs and economic benefits in each province to understand the mechanism and characteristics of inter-provincial environmental pollution movement. Based on the regional input–output model and an inventory we compiled of sulfur dioxide(SO2) emissions of air pollutants in 2012, we calculate the implied inter-provincial environmental pollution emissions and economic benefits from trade, based on production and consumption (supply-side and demand-side). In addition, the movement relationship is explored, and the cost and economic value-added indexes of air pollution control are further constructed to provide effective evidence for a reasonable division of responsibility for environmental pollution control. The results show that there are obvious environmental inequities in the regional trade process in each province, indicating that environmental pollution has been moved. Developed provinces have more economic benefits but pay less in the process of trading goods with less-developed provinces due to the advantages of their industrial structure, while the opposite is true for less-developed provinces. Finally, we propose corresponding policy recommendations to change this condition.

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    Authors: Yong Shi; Anda Tang; Tongsheng Yao;

    In China, environmental pollution responsibilities are divided according to administrative regions. However, because of the strong externality of environmental pollution, the movement of environmental pollution undoubtedly increases the complexity of pollution governance. To divide the responsibility of environmental pollution governance in each province, we effectively quantify the unequal relationship between environmental pollution costs and economic benefits in each province to understand the mechanism and characteristics of inter-provincial environmental pollution movement. Based on the regional input–output model and an inventory we compiled of sulfur dioxide(SO2) emissions of air pollutants in 2012, we calculate the implied inter-provincial environmental pollution emissions and economic benefits from trade, based on production and consumption (supply-side and demand-side). In addition, the movement relationship is explored, and the cost and economic value-added indexes of air pollution control are further constructed to provide effective evidence for a reasonable division of responsibility for environmental pollution control. The results show that there are obvious environmental inequities in the regional trade process in each province, indicating that environmental pollution has been moved. Developed provinces have more economic benefits but pay less in the process of trading goods with less-developed provinces due to the advantages of their industrial structure, while the opposite is true for less-developed provinces. Finally, we propose corresponding policy recommendations to change this condition.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Article . 2022 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jun He; Ke Wang; Jiangang Li;

    Pyro-breaker, a fast-responding, highly reliable and explosive-driven circuit breaker, is utilized in several Quench Protection Systems (QPS). The commutation process and its parameters are the main technical considerations in the process of designing a new pyro-breaker. The commutation parameters, such as the commutation time and the current change rate, are not only determined by the electrical parameters of the commutation circuit but also the arc behavior during the operation. The arc behavior is greatly affected by the structure and the driving mechanism of the Commutation Section (CS) in the pyro-breaker. The arc model was developed decades ago and the black-box arc model is considered a valid method to study arc behavior. In this paper, the Schavemaker black-box arc model, an improved Mayr-type arc model, is applied to study the commutation process of a newly designed pyro-breaker. Unlike normal circuit breakers, the arc discussed in this paper is discharged in deionized water. A parameter selection method is proposed. The practicability of the method is verified by numerical calculation in Power Systems Computer Aided Design (PSCAD) and experimentally.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2021 . Peer-reviewed
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    Article . 2021
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      Article . 2021 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jun He; Ke Wang; Jiangang Li;

    Pyro-breaker, a fast-responding, highly reliable and explosive-driven circuit breaker, is utilized in several Quench Protection Systems (QPS). The commutation process and its parameters are the main technical considerations in the process of designing a new pyro-breaker. The commutation parameters, such as the commutation time and the current change rate, are not only determined by the electrical parameters of the commutation circuit but also the arc behavior during the operation. The arc behavior is greatly affected by the structure and the driving mechanism of the Commutation Section (CS) in the pyro-breaker. The arc model was developed decades ago and the black-box arc model is considered a valid method to study arc behavior. In this paper, the Schavemaker black-box arc model, an improved Mayr-type arc model, is applied to study the commutation process of a newly designed pyro-breaker. Unlike normal circuit breakers, the arc discussed in this paper is discharged in deionized water. A parameter selection method is proposed. The practicability of the method is verified by numerical calculation in Power Systems Computer Aided Design (PSCAD) and experimentally.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2021 . Peer-reviewed
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    Authors: Ting Chen; Zhengming Yang; Yutian Luo; Wei Lin; +3 Authors

    In order to evaluate the displacement effect of four kinds of injection media in tight oil sandstone, water, active water, CO2, N2 flooding experiments were carried out in laboratory. Online Nuclear Magnetic Resonance (NMR) spectrometers combine the advantages of NMR technology and core displacement experiments. In the displacement experiment, NMR data of different injection volumes were obtained and magnetic resonance imaging (MRI) was carried out. The results showed that micro and sub-micropores provided 62–97% of the produced crude oil. The enhanced oil recovery ratio of active water flooding was higher than that of conventional water flooding up to 10%. The recovery ratio of gas flooding in micro and sub-micropores was 60–70% higher than that of water flooding. The recovery ratio of CO2 flooding was 10% higher than that of N2 flooding. The remaining oil was mainly distributed in pores larger than 0.1 μm. Under the same permeability level, the remaining oil saturation of cores after gas flooding was 10–25% lower than water flooding. From MRI images, the displacement effects from good to bad were as follows: CO2 flooding, N2 flooding, active water flooding, and conventional water flooding.

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    Authors: Ting Chen; Zhengming Yang; Yutian Luo; Wei Lin; +3 Authors

    In order to evaluate the displacement effect of four kinds of injection media in tight oil sandstone, water, active water, CO2, N2 flooding experiments were carried out in laboratory. Online Nuclear Magnetic Resonance (NMR) spectrometers combine the advantages of NMR technology and core displacement experiments. In the displacement experiment, NMR data of different injection volumes were obtained and magnetic resonance imaging (MRI) was carried out. The results showed that micro and sub-micropores provided 62–97% of the produced crude oil. The enhanced oil recovery ratio of active water flooding was higher than that of conventional water flooding up to 10%. The recovery ratio of gas flooding in micro and sub-micropores was 60–70% higher than that of water flooding. The recovery ratio of CO2 flooding was 10% higher than that of N2 flooding. The remaining oil was mainly distributed in pores larger than 0.1 μm. Under the same permeability level, the remaining oil saturation of cores after gas flooding was 10–25% lower than water flooding. From MRI images, the displacement effects from good to bad were as follows: CO2 flooding, N2 flooding, active water flooding, and conventional water flooding.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Authors: Bo Gao; Hongmei Shao; Jiyong Li; Haoyuan Jiang; +7 Authors

    Pore network modeling based on digital rock is employed to evaluate the mobility of shale oil in Qingshankou Formation, Songliao Basin, China. Computerized tomography technology is adopted in this work to reconstruct the digital rock of shale core. The pore network model is generated based on the computerized tomography data. We simulate the dynamics of fluid flow in a pore network model to evaluate the mobility of fluid in shale formation. The results show that the relative permeability of oil phase increases slowly in the initial stage of the displacement process, which is mainly caused by the poor continuity of the oil phase. In the later stages, with the increase in the oil phase continuity, the range of relative permeability increases. With the increase of organic matter content, the permeability of the water phase remains unchanged at low water saturation, but gradually increases at high water saturation. At the same time, it can be seen that, with the increase in organic matter content, the isosmotic point of the oil–water phase permeability shifts to the left, indicating that the wettability to water phase gradually weakens.

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    Authors: Bo Gao; Hongmei Shao; Jiyong Li; Haoyuan Jiang; +7 Authors

    Pore network modeling based on digital rock is employed to evaluate the mobility of shale oil in Qingshankou Formation, Songliao Basin, China. Computerized tomography technology is adopted in this work to reconstruct the digital rock of shale core. The pore network model is generated based on the computerized tomography data. We simulate the dynamics of fluid flow in a pore network model to evaluate the mobility of fluid in shale formation. The results show that the relative permeability of oil phase increases slowly in the initial stage of the displacement process, which is mainly caused by the poor continuity of the oil phase. In the later stages, with the increase in the oil phase continuity, the range of relative permeability increases. With the increase of organic matter content, the permeability of the water phase remains unchanged at low water saturation, but gradually increases at high water saturation. At the same time, it can be seen that, with the increase in organic matter content, the isosmotic point of the oil–water phase permeability shifts to the left, indicating that the wettability to water phase gradually weakens.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Authors: Shengpeng Xia; Anqing Zheng; Kun Zhao; Zengli Zhao; +1 Authors

    To reveal the effect of torrefaction pretreatment on pyrolysis and gasification reactivity of biomass, corn cob was first subjected to torrefaction pretreatment in a fixed-bed reactor at various reaction temperatures. The pyrolysis reactivity, kinetics, and gasification reactivity of torrefied corn cob were systematically assessed by various methods, proving that torrefaction pretreatment has a substantial influence on the physicochemical properties of corn cobs. The O/C and H/C molar ratios of corn cobs considerably drop with the increasing torrefaction temperature, and their higher heat-ing value (HHV) and energy density rise as well. It is found that torrefaction improves the pyrolysis reactivity of corn cobs because hemicellulose degradation is more severe than cellulose degradation during torrefaction, resulting in an increase in the percentage of cellulose in torrefied corn cobs. However, the severe depolymerization, polycondensation, and carbonization reaction during torre-faction of corn cobs at 280–300 °C can lead to a significant decline in the pyrolysis reactivity of corn cobs. Torrefaction pretreatment increases the pyrolysis activation energy of corn cobs, in addition to decreasing the char gasification reactivity of corn cob. The average char gasification reactivity of corn cobs drops when torrefaction severity increases. The passivation of active sites on the char surface may cause condensation and carbonation reactions of corn cobs during torrefaction. These findings provide new sights into the reasonable design of efficient torrefaction methods for appli-cation prior to pyrolysis and gasification of biomass.

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    Energies
    Article . 2022 . Peer-reviewed
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    Authors: Shengpeng Xia; Anqing Zheng; Kun Zhao; Zengli Zhao; +1 Authors

    To reveal the effect of torrefaction pretreatment on pyrolysis and gasification reactivity of biomass, corn cob was first subjected to torrefaction pretreatment in a fixed-bed reactor at various reaction temperatures. The pyrolysis reactivity, kinetics, and gasification reactivity of torrefied corn cob were systematically assessed by various methods, proving that torrefaction pretreatment has a substantial influence on the physicochemical properties of corn cobs. The O/C and H/C molar ratios of corn cobs considerably drop with the increasing torrefaction temperature, and their higher heat-ing value (HHV) and energy density rise as well. It is found that torrefaction improves the pyrolysis reactivity of corn cobs because hemicellulose degradation is more severe than cellulose degradation during torrefaction, resulting in an increase in the percentage of cellulose in torrefied corn cobs. However, the severe depolymerization, polycondensation, and carbonization reaction during torre-faction of corn cobs at 280–300 °C can lead to a significant decline in the pyrolysis reactivity of corn cobs. Torrefaction pretreatment increases the pyrolysis activation energy of corn cobs, in addition to decreasing the char gasification reactivity of corn cob. The average char gasification reactivity of corn cobs drops when torrefaction severity increases. The passivation of active sites on the char surface may cause condensation and carbonation reactions of corn cobs during torrefaction. These findings provide new sights into the reasonable design of efficient torrefaction methods for appli-cation prior to pyrolysis and gasification of biomass.

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    Energies
    Article . 2022 . Peer-reviewed
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    Energies
    Article . 2022
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      Article . 2022 . Peer-reviewed
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    Authors: Jian Wang; Peng Li; Weizheng Bai; Jun Lu; +3 Authors

    With the development of salt cavern gas storage construction technology, the construction of large-scale gas storage salt caverns using sediment voids is expected to solve the problem of low effective volume formation rate and poor construction economy of high-impurity salt mines. There are few studies on the long-term operation mechanical behavior of salt cavern gas storage under the influence of sediment accumulation currently. This paper studies the influence of sediment accumulation height, particle gradation, and operating pressure on the stability of salt caverns by constructing a coupling model of sediment particle discontinuous medium and surrounding rock continuous medium. The continuous-discontinuous coupling algorithm is suitable for analyzing the influence of particle accumulation height and particle gradation on the creep shrinkage of salt caverns. The increase of sediment accumulation height slows down the creep shrinkage of the bottom of the salt cavern, strengthens the restraining effect on the surrounding rock of the cavern, and moves the position of the maximum displacement of the surrounding rock to the upper part of the cavern; the sediment particle gradation has little effect on the cavern volume shrinkage rate, and the greater the coarse particle content, the smaller the cavern volume shrinkage rate; the greater the operating pressure, the more conducive to maintaining the stability of the cavern, slowing down the upward movement of the sediment body and increasing the gas storage space in the upper part of the cavern. This research results can provide a reference for evaluating the long-term operation stability of sediment-type high-impurity salt cavern gas storage.

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    https://doi.org/10.20944/prepr...
    Article . 2024 . Peer-reviewed
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    Energies
    Article . 2024
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    Authors: Jian Wang; Peng Li; Weizheng Bai; Jun Lu; +3 Authors

    With the development of salt cavern gas storage construction technology, the construction of large-scale gas storage salt caverns using sediment voids is expected to solve the problem of low effective volume formation rate and poor construction economy of high-impurity salt mines. There are few studies on the long-term operation mechanical behavior of salt cavern gas storage under the influence of sediment accumulation currently. This paper studies the influence of sediment accumulation height, particle gradation, and operating pressure on the stability of salt caverns by constructing a coupling model of sediment particle discontinuous medium and surrounding rock continuous medium. The continuous-discontinuous coupling algorithm is suitable for analyzing the influence of particle accumulation height and particle gradation on the creep shrinkage of salt caverns. The increase of sediment accumulation height slows down the creep shrinkage of the bottom of the salt cavern, strengthens the restraining effect on the surrounding rock of the cavern, and moves the position of the maximum displacement of the surrounding rock to the upper part of the cavern; the sediment particle gradation has little effect on the cavern volume shrinkage rate, and the greater the coarse particle content, the smaller the cavern volume shrinkage rate; the greater the operating pressure, the more conducive to maintaining the stability of the cavern, slowing down the upward movement of the sediment body and increasing the gas storage space in the upper part of the cavern. This research results can provide a reference for evaluating the long-term operation stability of sediment-type high-impurity salt cavern gas storage.

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    https://doi.org/10.20944/prepr...
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    Authors: Haobo Chen; Shangyu Liu; Yaoqiu Kuang; Jie Shu; +1 Authors

    Electricity consumption is closely linked to economic growth, social development, and carbon emissions. In order to fill the gap of previous studies on the decomposition of electricity consumption drivers that have not adequately considered carbon emission constraint, this study constructs the Kaya extended model of electricity consumption and analyzes the effects of drivers in industrial and residential sectors using the Logarithmic Mean Divisia Index (LMDI) method, and empirically explores the temporal and spatial differences in electricity consumption. Results show that: (1) During 2005–2021, the total final electricity consumption growth in Guangdong was much higher than that in Yunnan, but the average annual growth rate in Guangdong was lower, and the largest growth in both provinces was in the industrial sector. (2) The labor productivity level effect is the primary driver that increases total final electricity consumption (Guangdong: 78.5%, Yunnan: 87.1%), and the industrial carbon emission intensity effect is the primary driver that decreases total final electricity consumption (Guangdong: −75.3%, Yunnan: −72.3%). (3) The year-to-year effect of each driver by subsector is overall positively correlated with the year-to-year change in the corresponding driver, and declining carbon emission intensity is a major factor in reducing electricity consumption. (4) The difference in each effect between Guangdong and Yunnan is mainly determined by a change in the corresponding driver and subsectoral electricity consumption. Policy implications are put forward to promote energy conservation and the realization of the carbon neutrality goal.

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    Authors: Haobo Chen; Shangyu Liu; Yaoqiu Kuang; Jie Shu; +1 Authors

    Electricity consumption is closely linked to economic growth, social development, and carbon emissions. In order to fill the gap of previous studies on the decomposition of electricity consumption drivers that have not adequately considered carbon emission constraint, this study constructs the Kaya extended model of electricity consumption and analyzes the effects of drivers in industrial and residential sectors using the Logarithmic Mean Divisia Index (LMDI) method, and empirically explores the temporal and spatial differences in electricity consumption. Results show that: (1) During 2005–2021, the total final electricity consumption growth in Guangdong was much higher than that in Yunnan, but the average annual growth rate in Guangdong was lower, and the largest growth in both provinces was in the industrial sector. (2) The labor productivity level effect is the primary driver that increases total final electricity consumption (Guangdong: 78.5%, Yunnan: 87.1%), and the industrial carbon emission intensity effect is the primary driver that decreases total final electricity consumption (Guangdong: −75.3%, Yunnan: −72.3%). (3) The year-to-year effect of each driver by subsector is overall positively correlated with the year-to-year change in the corresponding driver, and declining carbon emission intensity is a major factor in reducing electricity consumption. (4) The difference in each effect between Guangdong and Yunnan is mainly determined by a change in the corresponding driver and subsectoral electricity consumption. Policy implications are put forward to promote energy conservation and the realization of the carbon neutrality goal.

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    Energies
    Article . 2023 . Peer-reviewed
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    Energies
    Article . 2023
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      Energies
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    Authors: Yong Li; Jue Yang; Wei Long Liu; Cheng Lin Liao;

    The lithium-ion battery is a complicated non-linear system with multi electrochemical processes including mass and charge conservations as well as electrochemical kinetics. The calculation process of the electrochemical model depends on an in-depth understanding of the physicochemical characteristics and parameters, which can be costly and time-consuming. We investigated the electrochemical modeling, reduction, and identification methods of the lithium-ion battery from the electrode-level to the system-level. A reduced 9th order linear model was proposed using electrode-level physicochemical modeling and the cell-level mathematical reduction method. The data-driven predictor-based subspace identification algorithm was presented for the estimation of lithium-ion battery model in the system-level. The effectiveness of the proposed modeling and identification methods was validated in an experimental study based on LiFePO4 cells. The accuracy and dynamic characteristics of the identified model were found to be much more likely related to the operating State of Charge (SOC) range. Experimental results showed that the proposed methods perform well with high precision and good robustness in the SOC range of 90% to 10%, and the tracking error increases significantly within higher (100–90%) or lower (10–0%) SOC ranges. Moreover, to achieve an optimal balance between high-precision and low complexity, statistical analysis revealed that the 6th, 3rd, and 5th order battery model is the optimal choice in the SOC range of 90% to 100%, 90% to 10%, and 10% to 0%, respectively.

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    Energies
    Article . 2020 . Peer-reviewed
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    Energies
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    Authors: Yong Li; Jue Yang; Wei Long Liu; Cheng Lin Liao;

    The lithium-ion battery is a complicated non-linear system with multi electrochemical processes including mass and charge conservations as well as electrochemical kinetics. The calculation process of the electrochemical model depends on an in-depth understanding of the physicochemical characteristics and parameters, which can be costly and time-consuming. We investigated the electrochemical modeling, reduction, and identification methods of the lithium-ion battery from the electrode-level to the system-level. A reduced 9th order linear model was proposed using electrode-level physicochemical modeling and the cell-level mathematical reduction method. The data-driven predictor-based subspace identification algorithm was presented for the estimation of lithium-ion battery model in the system-level. The effectiveness of the proposed modeling and identification methods was validated in an experimental study based on LiFePO4 cells. The accuracy and dynamic characteristics of the identified model were found to be much more likely related to the operating State of Charge (SOC) range. Experimental results showed that the proposed methods perform well with high precision and good robustness in the SOC range of 90% to 10%, and the tracking error increases significantly within higher (100–90%) or lower (10–0%) SOC ranges. Moreover, to achieve an optimal balance between high-precision and low complexity, statistical analysis revealed that the 6th, 3rd, and 5th order battery model is the optimal choice in the SOC range of 90% to 100%, 90% to 10%, and 10% to 0%, respectively.

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    Energies
    Article . 2020 . Peer-reviewed
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    Energies
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    Energies
    Article . 2020
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      Article . 2020
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    Authors: Donghuan Han; Wei Xiong; Tongwen Jiang; Shusheng Gao; +4 Authors

    Although improving the recovery of water-invaded gas reservoirs has been extensively studied in the natural gas industry, the nature of the efficiency of water-invaded gas recovery remains uncertain. Low-field nuclear magnetic resonance (NMR) can be used to clearly identify changes in water saturation in the core during high-pressure water-invasion gas. Here, we provide four types of water-invasion gas experiments (spontaneous imbibition, atmospheric pressure, high-pressure approximate equilibrium, and depletion development water-invasion gas) to reveal the impact of the water-invasion gas efficiency on the recovery of water-invasion gas reservoirs. NMR suggested that imbibition mainly occurs in medium to large pores and that residual gas remains mainly in large pores. The amount of gas driven out from the large pores by imbibition was much greater than that driven out from the small pores. Our findings indicate that the initial gas saturation, contact surface, and permeability are the main factors controlling the residual gas saturation, suggesting that a reasonable initial water saturation should be established before the water-invasion gas experiments. Additionally, the water-invasion gas efficiency at high pressures can be more reliably obtained than that at normal pressures. After the high-pressure approximate equilibrium water invasion for gas displacement, a large amount of residual gas remains in the relatively larger pores of the core, with a residual gas saturation of 42%. In contrast to conventional experiments, the residual gas saturation and water displacement efficiency of the high-pressure approximate equilibrium water invasion for gas displacement did not exhibit a favorable linear relationship with the permeability. The residual gas saturation ranged from 34 to 43% (avg. 38%), while the water displacement efficiency ranged from 32 to 45% (avg. 40%) in the high-pressure approximate equilibrium water invasion for gas displacement. The residual gas saturation in the depletion development water-invasion gas experiment was 26–40% (average: 33%), with an efficiency ranging from 45 to 50% (average: 48%), indicating that the depletion development experiment is closer to the actual development process of gas reservoirs. Our findings provide novel insights into water-invasion gas efficiency, providing robust estimates of the recovery of water-invasion gas reservoirs.

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    Article . 2023 . Peer-reviewed
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    Authors: Donghuan Han; Wei Xiong; Tongwen Jiang; Shusheng Gao; +4 Authors

    Although improving the recovery of water-invaded gas reservoirs has been extensively studied in the natural gas industry, the nature of the efficiency of water-invaded gas recovery remains uncertain. Low-field nuclear magnetic resonance (NMR) can be used to clearly identify changes in water saturation in the core during high-pressure water-invasion gas. Here, we provide four types of water-invasion gas experiments (spontaneous imbibition, atmospheric pressure, high-pressure approximate equilibrium, and depletion development water-invasion gas) to reveal the impact of the water-invasion gas efficiency on the recovery of water-invasion gas reservoirs. NMR suggested that imbibition mainly occurs in medium to large pores and that residual gas remains mainly in large pores. The amount of gas driven out from the large pores by imbibition was much greater than that driven out from the small pores. Our findings indicate that the initial gas saturation, contact surface, and permeability are the main factors controlling the residual gas saturation, suggesting that a reasonable initial water saturation should be established before the water-invasion gas experiments. Additionally, the water-invasion gas efficiency at high pressures can be more reliably obtained than that at normal pressures. After the high-pressure approximate equilibrium water invasion for gas displacement, a large amount of residual gas remains in the relatively larger pores of the core, with a residual gas saturation of 42%. In contrast to conventional experiments, the residual gas saturation and water displacement efficiency of the high-pressure approximate equilibrium water invasion for gas displacement did not exhibit a favorable linear relationship with the permeability. The residual gas saturation ranged from 34 to 43% (avg. 38%), while the water displacement efficiency ranged from 32 to 45% (avg. 40%) in the high-pressure approximate equilibrium water invasion for gas displacement. The residual gas saturation in the depletion development water-invasion gas experiment was 26–40% (average: 33%), with an efficiency ranging from 45 to 50% (average: 48%), indicating that the depletion development experiment is closer to the actual development process of gas reservoirs. Our findings provide novel insights into water-invasion gas efficiency, providing robust estimates of the recovery of water-invasion gas reservoirs.

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    Energies
    Article . 2023 . Peer-reviewed
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    Authors: Nengxiong Xu; Cheng Cheng; Xiao Li; Bo Zheng;

    Dilation behavior is of great importance for reasonable modeling of the stability of the host rock of the repository for high-level radioactive waste disposal. It is a suitable method for carrying out direct shear experiments to analyze the dilation behavior of rock with well understood physical meanings. Based on a series of direct shear experiments on granite samples from the Alxa candidate area under different normal stresses, the shear stress‒shear strain and shear stress‒normal strain relations have been studied in detail. Five typical stages have been divided associated with the fracturing process and deformation behaviors of the granite samples during the experimental process, and the method to determine the typical stress thresholds has been proposed. It has also been found that the increasing normal stress may reduce the maximum dilation angle, and when the normal stress is relatively lower, the negative dilation angle may occur during the post-peak stage. According to the data collected from the direct shear tests, an empirical model of the mobilized dilation angle dependent on normal stress and plastic shear strain is proposed. This mobilized dilation angle has clear physical meanings and can be used in plastic constitutive models of the host rock of the repository, and this analysis can also be put forward to other types of geomechanical problems, including the deformation behaviors related to landslide, earthquake, and so on.

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    Authors: Nengxiong Xu; Cheng Cheng; Xiao Li; Bo Zheng;

    Dilation behavior is of great importance for reasonable modeling of the stability of the host rock of the repository for high-level radioactive waste disposal. It is a suitable method for carrying out direct shear experiments to analyze the dilation behavior of rock with well understood physical meanings. Based on a series of direct shear experiments on granite samples from the Alxa candidate area under different normal stresses, the shear stress‒shear strain and shear stress‒normal strain relations have been studied in detail. Five typical stages have been divided associated with the fracturing process and deformation behaviors of the granite samples during the experimental process, and the method to determine the typical stress thresholds has been proposed. It has also been found that the increasing normal stress may reduce the maximum dilation angle, and when the normal stress is relatively lower, the negative dilation angle may occur during the post-peak stage. According to the data collected from the direct shear tests, an empirical model of the mobilized dilation angle dependent on normal stress and plastic shear strain is proposed. This mobilized dilation angle has clear physical meanings and can be used in plastic constitutive models of the host rock of the repository, and this analysis can also be put forward to other types of geomechanical problems, including the deformation behaviors related to landslide, earthquake, and so on.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Authors: Yong Shi; Anda Tang; Tongsheng Yao;

    In China, environmental pollution responsibilities are divided according to administrative regions. However, because of the strong externality of environmental pollution, the movement of environmental pollution undoubtedly increases the complexity of pollution governance. To divide the responsibility of environmental pollution governance in each province, we effectively quantify the unequal relationship between environmental pollution costs and economic benefits in each province to understand the mechanism and characteristics of inter-provincial environmental pollution movement. Based on the regional input–output model and an inventory we compiled of sulfur dioxide(SO2) emissions of air pollutants in 2012, we calculate the implied inter-provincial environmental pollution emissions and economic benefits from trade, based on production and consumption (supply-side and demand-side). In addition, the movement relationship is explored, and the cost and economic value-added indexes of air pollution control are further constructed to provide effective evidence for a reasonable division of responsibility for environmental pollution control. The results show that there are obvious environmental inequities in the regional trade process in each province, indicating that environmental pollution has been moved. Developed provinces have more economic benefits but pay less in the process of trading goods with less-developed provinces due to the advantages of their industrial structure, while the opposite is true for less-developed provinces. Finally, we propose corresponding policy recommendations to change this condition.

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    Authors: Yong Shi; Anda Tang; Tongsheng Yao;

    In China, environmental pollution responsibilities are divided according to administrative regions. However, because of the strong externality of environmental pollution, the movement of environmental pollution undoubtedly increases the complexity of pollution governance. To divide the responsibility of environmental pollution governance in each province, we effectively quantify the unequal relationship between environmental pollution costs and economic benefits in each province to understand the mechanism and characteristics of inter-provincial environmental pollution movement. Based on the regional input–output model and an inventory we compiled of sulfur dioxide(SO2) emissions of air pollutants in 2012, we calculate the implied inter-provincial environmental pollution emissions and economic benefits from trade, based on production and consumption (supply-side and demand-side). In addition, the movement relationship is explored, and the cost and economic value-added indexes of air pollution control are further constructed to provide effective evidence for a reasonable division of responsibility for environmental pollution control. The results show that there are obvious environmental inequities in the regional trade process in each province, indicating that environmental pollution has been moved. Developed provinces have more economic benefits but pay less in the process of trading goods with less-developed provinces due to the advantages of their industrial structure, while the opposite is true for less-developed provinces. Finally, we propose corresponding policy recommendations to change this condition.

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