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It is now environmentally desirable and legally mandatory to add renewable fuels such as ethanol or ethyl tert-butyl ether to gasoline. However, biofuels affect, among other properties, the distillation curve of gasoline, which is subject to strict regulations. This work presents a simple mathematical model capable of accurately predicting the influence that the addition of these oxygenates has on the distillation curve. In order to address this issue, it is essential to find a simple mathematical correlation between the boiling temperatures of the hydrocarbons present in gasoline and the properties (boiling temperature and volume or molar concentration of ethanol) of the corresponding azeotropic mixtures formed with ethanol. Power functions have been assumed to model the temperature composition diagrams of the vapour-liquid equilibrium. Experimental data previously published by these and other authors have been used to fit and validate the model. The results provided by the mathematical model can be of great interest to understand the process of fuel evaporation in spark-ignition engines or the adjustment of distillation cuts in refineries, in order to comply with the regulations, in terms of the distillation curve, after adding ethanol or ethyl tert-butyl ether.

Originally developed and validated at the Cabauw (Netherlands) topographically flat onshore location, the alpha-I wind resource extrapolating method was tested at the FINO3 offshore site in the North Sea (Germany). The aim was to prove its validity also when applied over a substantially different environment in terms of surface characteristics and stability conditions. Data from local mast at 30, 80, and 100 m were used, with extrapolations to 80-m and 100-m turbine hub heights accomplished based on 30-m turbulence intensity observations. Trained over a 2-year period (2011-2012), the method was validated on year 2013. Similarly to the onshore application, the method was reliable in extrapolating wind speed to both 80 m and 100 m, with bias within 5%, NRMSE = 0.20 and r = 0.94. Conversely, scores were largely better than at the onshore site in predicting the annual energy yield, biased by 0.41-1.02% at 80 m, and 1.12-1.36% at 100 m. The method proved to be highly sensitive to the stability classification, as not considering this option increased its biases to 4.51-5.93% at 80 m, and 7.46-8.23% at 100 m. Method's reliability might suitably help reduce the number of masts installed throughout a large offshore area.

Artículos en revistas There has been total unanimity about the vital importance of reliability of supply since the beginning of the electricity sector deregulation process. This paper describes the procedure proposed by Pérez-Arriaga et al. [2005. White paper for the reform of the regulatory scheme of the power generation in Spain. For the Ministry of Industry, Tourism and Trade of Spain (in Spanish)] to improve upon the current scheme to guarantee a reasonable reserve margin, the capacity payment mechanism. This alternative design introduces improvements aimed at guaranteeing at least a minimum capacity reserve margin, as well as at providing a strong incentive for generating units to be available when needed, namely, in situations when supply is likely to be insufficient to meet the total demand. info:eu-repo/semantics/publishedVersion

The search for affordable high performance electrode materials in photoelectrochemical hydrogen production by solar water splitting is an ongoing quest. Hematite is a photoanode material with an electronic band gap suitable for efficient absorption of visible light in a photoelectrochemical cell (PEC). Although its poor electronic structure makes hematite a controversial candidate for PEC, it remains promising because it is an earth abundant, chemically stable and low cost material – necessary prerequisites for PEC to become a competitive cost-efficient solar fuel economy. In addition to reviewing some recent PEC research on hematite and its relevant physical and chemical characteristics, we show how hematite obtained by a low cost synthesis can be refined by hydrothermal treatment and further functionalized by coating with phycocyanin, a light harvesting protein known for photosynthesis in blue-green algae.

Capítulos en libros This paper presents a general method to convert State feedback controllers to damp power system electromechanical oscillations to the standard structure formed by an Automatic Voltage Regulator (AVR) and a Power System Stabilizer (PSS). The proposed conversion method is based on least squares fitting in the frequency domain. info:eu-repo/semantics/publishedVersion

It is widely accepted that medium-term generation planning can be advantageously modeled through market equilibrium representation. There exist several methods to define and solve this kind of equilibrium in a deterministic way. Medium-term planning is strongly affected by uncertainty in market and system conditions; thus, extensions of these models are commonly required. The main variables that should be considered as subject to uncertainty include hydro conditions, demand, generating units' failures, and fuel prices. This paper presents a model to represent a medium-term operation of the electrical market that introduces this uncertainty in the formulation in a natural and practical way. Utilities are explicitly considered to be maximizing their expected profits, and biddings are represented by means of a conjectural variation. Market equilibrium conditions are introduced by means of the optimality conditions of a problem, which has a structure that strongly resembles classical optimization of hydrothermal coordination. A tree-based representation to include stochastic variables and a model based on it are introduced. This approach to market representation provides three main advantages: Robust decisions are obtained; technical constraints are included in the problem in a natural way, additionally obtaining dual information; and large-size problems representing real systems in detail can be addressed.

Abstract From the sustainable perspective, the optimum thickness calculations of the buildings envelope insulation materials published in scientific journals suffer a number of notable shortcomings. The most relevant are the short amortization time periods and the prevalence of economic criterion. The work presented shows that an increase from 20 to 50 years in the amortization time period involves, in some cases, to double the value of the optimum thickness. Moreover, the thicknesses calculated applying energetic or environmental criteria for the optimization give, in some cases, results 10 times higher than the ones obtained using the economic argument. The type of insulation materials (especially their different characteristics at the manufacturing stage) and the calculation conditions (e.g. Degree-Days zone) also affect optimum thicknesses determination.

This paper proposes a linear programming problem to find the optimal planning and operation of aggregated distributed energy resources (DER), managed by an aggregator that participates in the day-ahead wholesale electricity market as a price-maker agent. The proposed model analyzes the impact of the size of the aggregated resources and gives the optimal planning and management of DER systems, and the corresponding energy transactions in the wholesale day-ahead market. The results suggest that when the aggregated resources are large enough, DER systems can achieve up to 32% extra economic benefits depending on the market share, compared with a business-as-usual approach (not implementing DER systems). info:eu-repo/semantics/draft