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Hydraulic fracturing drilling technology can cause a high risk of surface spill accidents and thus water contamination. Climate change together with the high water demand and rapid increase in industrial and agricultural activities are valued reasons why we should all care about the availability of water resources and protect them from contamination. Hence, the purpose of this study is to estimate the risk associated with a site contaminated with benzene from oil spillage and its potential impact on groundwater. This study focused on investigating the impact of soil variability and water table depth on groundwater contamination. Temperature-dependent parameters, such as soil water content and the diffusion of pollutants, were considered as key input factors for the HYDRUS 1D numerical model to simulate benzene migration through three types of soil (loamy, sandy clay loam, and silt loam) and evaluate its concentration in the water aquifer. The results indicated that an anticipated increase in earth’s average surface temperature by 4 °C due to climate change could lead to a rise in the level of groundwater pollution in the study area by 0.017 mg/L in loamy soil, 0.00046 mg/L in sandy clay loam soil, and 0.00023 mg/L in silt loam soil. It was found that climate change can reduce the amount of benzene absorbed from 10 to 0.07% in loamy soil, 14 to 0.07% in sandy clay loam soil, and 60 to 53% in silt loam soil. The results showed that the soil properties and solute characteristics that depend on the temperature have a major and important role in determining the level of groundwater pollutants.

AbstractIron-acceptor (FeAc) pair association has been studied in compensated n-type silicon. A dynamic approach, based on the charge carrier recombination rates over the Fei trap level, leads to an explanation of the observed FeAc pairing reaction in compensated n-type silicon and extends the understanding of FeAc pairing kinetics. Association kinetics was used to measure a height dependent acceptor concentration profile. Even in compensated n-type silicon good agreement with expected concentrations is found.

Characteristics of Tm:YAG ceramic for high efficient 2-μm lasers are analyzed. Efficient diode end-pumped continuous-wave and Q-switched Tm:YAG ceramic lasers are demonstrated. At the absorbed pump power of 53.2W, the maximum continuous wave (cw) output power of 17.2 W around 2016 nm was obtained with the output transmission of 5%. The optical conversion efficiency is 32.3%, corresponding to a slope efficiency of 36.5%. For Q-switched operation, the shortest width of 69 ns was achieved with the pulse repetition frequency of 500 Hz and single pulse energy of 20.4 mJ, which indicates excellent energy storage capability of the Tm:YAG ceramic.

This study evaluated the environmental conditions of two watersheds selected on the basis of similarities in land use. The environmental conditions of the watersheds were analyzed using two geoprocessing methods and in situ evaluations by applying the rapid assessment protocol (RAP). Geospatial image processing was used to analyze land use, slope, soil classification, and rainfall, while RAP was used to evaluate the connectivity and size of riparian corridors. The results revealed varied uses of land with the landscape matrix in both watersheds, composed of agriculture, pasture, and urban centers. Urban centers were defined as spots and riparian zones as corridors. The analysis of environmental fragility considering all the geospatial variables, classified both watersheds as having medium fragility. The most fragile sites were the urban centers, which had a high slope and degraded riparian zone. Onsite assessments have shown that corridors do not have the size required by legislation; they are fragmented and unstructured, and they contain exotic species. We also propose that a multi-factorial approach be used to evaluate watersheds, associating geospatial assessments and onsite analyses that consider the limitations pointed out in each protocol. This reduces sampling errors and shows the actual state of conservation in riparian zones.

Abstract. Regional land carbon budgets provide insights on the spatial distribution of the land uptake of atmospheric carbon dioxide, and can be used to evaluate carbon cycle models and to define baselines for land-based additional mitigation efforts. The scientific community has been involved in providing observation-based estimates of regional carbon budgets either by downscaling atmospheric CO2 observations into surface fluxes with atmospheric inversions, by using inventories of carbon stock changes in terrestrial ecosystems, by upscaling local field observations such as flux towers with gridded climate and remote sensing fields or by integrating data-driven or process-oriented terrestrial carbon cycle models. The first coordinated attempt to collect regional carbon budgets for nine regions covering the entire globe in the RECCAP-1 project has delivered estimates for the decade 2000–2009, but these budgets were not comparable between regions, due to different definitions and component fluxes reported or omitted. The recent recognition of lateral fluxes of carbon by human activities and rivers, that connect CO2 uptake in one area with its release in another also requires better definition and protocols to reach harmonized regional budgets that can be summed up to the globe and compared with the atmospheric CO2 growth rate and inversion results. In this study, for the international initiative RECCAP-2 coordinated by the Global Carbon Project, which aims as an update of regional carbon budgets over the last two decades based on observations, for 10 regions covering the globe, with a better harmonization that the precursor project, we provide recommendations for using atmospheric inversions results to match bottom-up carbon accounting and models, and we define the different component fluxes of the net land atmosphere carbon exchange that should be reported by each research group in charge of each region. Special attention is given to lateral fluxes, inland water fluxes and land use fluxes.

AbstractThis work reports the synthesis, characterization, photophysical, and photovoltaic properties of five new thieno[3,2‐b][1]benzothiophene isoindigo (TBTI)‐containing low bandgap donor–acceptor conjugated polymers with a series of comonomers and different side chains. When TBTI is combined with different electron‐rich moieties, even small structural variations can have significant impact on thin film morphology of the polymer:phenyl C70 butyric acid methyl ester (PCBM) blends. More importantly, high‐resolution electron energy loss spectroscopy is used to investigate the phase‐separated bulk heterojunction domains, which can be accurately and precisely resolved, enabling an enhanced correlation between polymer chemical structure, photovoltaic device performance, and morphology.

The performance of dual chambered mediator-less microbial fuel cell (MFC) operated under batch mode was evaluated under different operating temperatures, ranging between 20 and 55 °C, with step increase in temperature of 5 °C. Synthetic wastewater with sucrose as carbon source having chemical oxygen demand (COD) of 519–555 mg/L was used in the study. Temperature was a crucial factor in the performance of MFCs for both COD removal and electricity production. The MFC demonstrated highest COD removal efficiency of 84% and power density normalized to the anode surface area of 34.38 mW/m2 at operating temperature of 40 °C. Higher VSS to SS ratio was observed at the operating temperature between 35 and 45 °C. Under different operating temperatures the observed sludge yield was in the range of 0.05 to 0.14 g VSS/g COD removed. The maximum Coulombic and energy efficiencies were obtained at 40 °C, with values of 7.39 and 13.14%, respectively. Internal resistance of the MFC decreased with increase in operating temperature. Maximum internal resistance of 1,150 Ω was observed when the MFC was operated at 20 °C; whereas the minimum internal resistance (552 Ω) was observed at 55 °C.