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  • Energy Research
  • 2021-2025
  • physical sciences
  • 7. Clean energy
  • 13. Climate action
  • 14. Life underwater

  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Sirko Bartholomay; Sascha Krumbein; Sebastian Perez‐Becker; Rodrigo Soto‐Valle; +3 Authors

    AbstractThis paper presents an experimental assessment of a blended fatigue‐extreme controller for load control employing trailing edge flaps on a lab‐scale wind turbine. The controller blends between a repetitive model predictive controller that targets fatigue loads and a dedicated extreme load controller, which consists of a simple on‐off load control strategy. The Fatigue controller uses the flapwise blade root bending moments of the three blades as input sensors. The Extreme controller additionally uses on‐blade angle of attack and velocity measurements as well as acceleration measurements to detect extreme events and to allow for a fast reaction. The experiments are conducted on the Berlin Research Turbine within the large wind tunnel of the TU Berlin. In order to reproduce test cases with deterministic extreme wind conditions that follow industry standards, the wind tunnel was redesigned. The analyzed test cases are extreme direction change, extreme coherent gust, extreme operating gust and extreme coherent gust with direction change. The test cases are analyzed by on‐blade angle of attack and velocity measurements. The load control performance of the Blended controller is compared to the pure fatigue oriented and the pure extreme load controller. The Blended controller achieves a maximum flapwise blade root bending moment reduction of 23%, which is comparable to the reduction achieved by the Extreme controller.

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    Wind Energy
    Article . 2022 . Peer-reviewed
    License: CC BY NC
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    https://dx.doi.org/10.14279/de...
    Article . 2022
    License: CC BY NC
    Data sources: Datacite
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    Wind Energy
    Article . 2023
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Wind Energyarrow_drop_down
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      Wind Energy
      Article . 2022 . Peer-reviewed
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      https://dx.doi.org/10.14279/de...
      Article . 2022
      License: CC BY NC
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      Wind Energy
      Article . 2023
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    Authors: Shaohua Guan; Xiaocun Guan; Baoqi Wu; Jingbin Shi;

    The influence of electromagnetic induction coil launcher (EICL) system parameters on the launch performance was analyzed, and a method for measuring the launch performance of an EICL system with a muzzle velocity and energy conversion efficiency was proposed. The EICL system mainly includes a pulse power supply and launcher. The parameters of the pulse power supply mainly include the discharge voltage and the capacitance value of the capacitor bank. The structural parameters of the launcher mainly include the bore size of the launcher, the air gap length between the armature and the drive coil, the length and width of the drive coil, and the trigger position of the armature. Change in single or multiple parameters in the launch system will influence the launch performance. The influence of single or multiple parameters on the launch performance was summarized, and the physical law as analyzed. The influence law of the EICL system parameters on the launch performance was obtained, which lays a theoretical foundation for the optimization design of EICL. Finally, experimental verification was carried out by a single-stage test platform.

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    Energies
    Article . 2022 . Peer-reviewed
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    Energies
    Article . 2022
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
      Article . 2022 . Peer-reviewed
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      Energies
      Article . 2022
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jia, Zhaolin; Wu, Han; Chen, Hao; Li, Wei; +5 Authors

    The tension legs are the essential parts of the tension legs platform-type (TLP-type) floating offshore wind turbine (FOWT) against the extra buoyancy of FOWT. Therefore, the TLP-type FOWT will face the risk of tension leg failure. However, there are seldom analyses on the hydrodynamic response and tension leg failure performance of FOWT with inclined tension legs. In this paper, a hydrodynamic model was established using three-dimensional hydrodynamic theory and applied in the motion response and tension analyses of FOWT with conventional and new tension leg arrangements on Moses. The influence of draft and tension leg arrangement on the performance of FOWT with inclined tension legs were studied. The optimum draft was the height of the column and lower tensions were obtained for the new tension leg arrangement. Moreover, the tension leg failure performance of FOWT with inclined tension legs was evaluated under different failure conditions. The results illustrated that the FOWT with the new tension leg arrangement can still operate safely after one tension leg fails.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ DR-NTU (Digital Repo...arrow_drop_down
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    Energies
    Article . 2022 . Peer-reviewed
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    Energies
    Article . 2022
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ DR-NTU (Digital Repo...arrow_drop_down
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      Energies
      Article . 2022 . Peer-reviewed
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  • Authors: Byungsul Min; Matthias Muller; Bettina Wolpensinger; Gerd Fischer; +3 Authors

    This article investigates the impact of the back-surface-field (BSF) thickness variation within a local aluminum contact on the performance of passivated emitter and rear contact solar cells. A significant difference of BSF thickness between contact endings and the center of dash-shaped contacts is verified experimentally by a comprehensive statistical analysis using scanning electron microscopy. The impact of local BSF thickness differences on the cell performance is studied with 3-D technology computer-aided design (TCAD) device simulations. Several device parameters such as BSF thicknesses, the doping concentration in the BSF profile at rear contacts, or the metallized area fraction at the cell rear side are varied. Our simulation study shows that the open-circuit voltage is mainly affected by locally reduced BSF thicknesses, resulting in an efficiency loss up to 0.14%abs or 0.84%abs, respectively, if an area fraction of 1% or 20% within a local contact has reduced BSF thicknesses. This effect can be minimized either by reducing the metallized area fraction at the cell rear side or by increasing the doping concentration in the BSF profile at aluminum rear contacts. In addition, we demonstrate that the 3-D simulations can be approximated with 2-D simulations by applying a single doping profile with an average BSF thickness, calculated with the harmonic mean.

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Tarek O. Abdul Fattah; Janet Jacobs; Vladimir P. Markevich; Nikolay V. Abrosimov; +3 Authors

    Before lower purity, lower cost silicon (Si) materials, such as compensated Si, can play a role in the terawatt-level (TW) capacity of photovoltaics, a better understanding of the fundamental properties of impurities in compensated Si is essential. In this work, high-resolution photoluminescence (PL) has been used to study the charge carrier radiative recombination through Donor-Acceptor pairs (DAPs) in phosphorus (P) and gallium (Ga) co-doped Si material grown for solar cell applications. The high spectral resolution of our PL system, 0.06 meV, enables us to overcome hitherto prior issues of overlapping spectral lines, giving access to extremely fine structures associated with DA pair (DAP) recombination. Our results confirm the presence of three broad bands and a discrete line structure related to DAP luminescence. The comparison of the discrete line structure due to DAPs recombination in the PL spectra with the theoretically predicted one allows the accurate determination of the Ga ionization energy. Temperature-dependent PL is then used to understand the thermally-induced changes in the DAP luminescence. In particular, we observe that the radiative recombination channel remains active for distant DAPs up to ∼40 K, unlike that for close-range DAPs for which the radiative channel is quenched after only slight increases in the temperature range 10–25 K. Furthermore, the analysis of the temperature dependent changes in the PL intensity of the broad DAP bands up to ∼200 K is used to derive the ionization energy of P donors in compensated Si material. In light of this important information, the significance of using high resolution PL to analyse spectral features in compensated Si is demonstrated.

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    Journal of Science: Advanced Materials and Devices
    Article . 2023 . Peer-reviewed
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      Journal of Science: Advanced Materials and Devices
      Article . 2023 . Peer-reviewed
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    Authors: Simona Breidokaite; Gediminas Stankunas;

    In fusion devices, such as European Demonstration Fusion Power Reactor (EU DEMO), primary neutrons can cause material activation due to the interaction between the source particles and the targeting material. Subsequently, the reactor’s inner components become activated. For safety and safe performance purposes, it is necessary to evaluate neutron-induced activities. Activities results from divertor reflector and liner plates are presented in this work. The purpose of liner shielding plates is to protect the vacuum vessel and magnet coils from neutrons. As for reflector plates, the function is to shield the cooling components under plasma-facing components from alpha particles, thermal effects, and impurities. Plates are made of Eurofer with a 3 mm layer of tungsten, while the water is used for cooling purposes. The calculations were performed using two EU DEMO MCNP (Monte Carlo N-Particles) models with different breeding blanket configurations: helium-cooled pebble bed (HCPB) and water-cooled lithium lead (WCLL). The TENDL–2017 nuclear data library has been used for activation reactions cross-sections and nuclear reactions. Activation calculations were performed using the FISPACT-II code at the end of irradiation for cooling times of 0 s–1000 years. Radionuclide analysis of divertor liner and reflector plates is also presented in this paper. The main radionuclides, with at least 1% contribution to the total value of activation characteristics, were identified for the previously mentioned cooling times.

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    Energies
    Article . 2021 . Peer-reviewed
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    Energies
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    Energies
    Article . 2021
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      Energies
      Article . 2021 . Peer-reviewed
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      Energies
      Article . 2021
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    Authors: Md. Shofiqul Islam;

    Thin-film organic solar cell (OSC) performances have been investigated in detail by improved analytical computation in this work. The generation of excitons inside OSC has been estimated by using the optical transfer matrix method (OTMM) to include the optical phenomena of the incident light. The dissociation of these excitons into free charge carriers has been investigated to find the most appropriate one. OSC performances have been evaluated by an improved analytical solution of electrical transport equations including (i) exciton generation obtained from OTMM, (ii) dissociation probability incorporating Gaussian distribution to account for the natural fact of the difference in photon-energy producing excitons, (iii) recombination of charge carriers, all together. OSC properties such as JSC, VOC, FF, PCE, Pmax, absorbance, and quantum efficiency have been investigated with the variation of different parameters; this might be useful to improve OSC. Again, the presented detailed derivations of analytical expressions would be helpful for clear understanding.

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    Energies
    Article . 2021 . Peer-reviewed
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    Article . 2021
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      Article . 2021
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    Authors: C Salazar Mejía; T Niehoff; M Straßheim; E Bykov; +3 Authors

    Abstract Magnetic refrigeration is a highly active field of research. The recent studies in materials and methods for hydrogen liquefaction and innovative techniques based on multicaloric materials have significantly expanded the scope of the field. For this reason, the proper characterization of materials is now more crucial than ever. This makes it necessary to determine the magnetocaloric and other physical properties under various stimuli such as magnetic fields and mechanical loads. In this work, we present an overview of the characterization techniques established at the Dresden High Magnetic Field Laboratory in recent years, which specializes in using pulsed magnetic fields. The short duration of magnetic-field pulses, lasting only some ten milliseconds, simplifies the process of ensuring adiabatic conditions for the determination of temperature changes, Δ T a d . The possibility to measure in the temperature range from 10 to 400 K allows us to study magnetocaloric materials for both room-temperature applications and gas liquefaction. With magnetic-field strengths of up to 50 T, almost every first-order material can be transformed completely. The high field-change rates allow us to observe dynamic effects of phase transitions driven by nucleation and growth as well. We discuss the experimental challenges and advantages of the investigation method using pulsed magnetic fields. We summarize examples for some of the most important material classes including Gd, Laves phases, La–Fe–Si, Mn–Fe–P–Si, Heusler alloys and Fe–Rh. Further, we present the recent developments in simultaneous measurements of temperature change, strain, and magnetization, and introduce a technique to characterize multicaloric materials under applied magnetic field and uniaxial load. We conclude by demonstrating how the use of pulsed fields opens the door to new magnetic-refrigeration principles based on multicalorics and the ‘exploiting-hysteresis’ approach.

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    JPhys Energy
    Article . 2023 . Peer-reviewed
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    JPhys Energy
    Article . 2023
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      JPhys Energy
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      JPhys Energy
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    Authors: Xiaonan Lu; Lu Deng; Sarah A. Saslow; Hongshen Liu; +7 Authors

    Vanadium-containing glasses have aroused interest in several fields such as electrodes for energy storage, semiconducting glasses, and nuclear waste disposal. The addition of V2O5, even in small amounts, can greatly alter the physical properties and chemical durability of glasses; however, the structural role of vanadium in these multicomponent glasses and the structural origins of these property changes are still poorly understood. We present a comprehensive study that integrates advanced characterizations and atomistic simulations to understand the composition-structure-property relationships of a series of vanadium-containing aluminoborosilicate glasses. UV-vis spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption near-edge structure (XANES) have been used to investigate the complex distribution of vanadium oxidation states as a function of composition in a series of six-component aluminoborosilicate glasses. High-energy X-ray diffraction and molecular dynamics simulations were performed to extract the detailed short- and medium-range atomistic structural information such as bond distance, coordination number, bond angle, and network connectivity, based on recently developed vanadium potential parameters. It was found that vanadium mainly exists in two oxidation states: V5+ and V4+, with the former being dominant (∼80% from XANES) in most compositions. V5+ ions were found to exist in 4-, 5-, and 6-fold coordination, while V4+ ions were mainly in 4-fold coordination. The percentage of 4-fold-coordinated boron and network connectivity initially increased with increasing V2O5 up to around 5 mol % but then decreased with higher V2O5 contents. The structural role of vanadium and the effect on glass structure and properties are discussed, providing insights into future studies of sophisticated structural descriptors to predict glass properties from composition and/or structure and aiding the formulation of borosilicate glasses for nuclear waste disposal and other applications.

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    The Journal of Physical Chemistry B
    Article . 2021 . Peer-reviewed
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    Authors: William J. Peplinski; Jesse Roberts; Geoff Klise; Sharon Kramer; +3 Authors

    Costs to permit Marine Energy projects are poorly understood. In this paper we examine environmental compliance and permitting costs for 19 projects in the U.S., covering the last 2 decades. Guided discussions were conducted with developers over a 3-year period to obtain historical and ongoing project cost data relative to environmental studies (e.g., baseline or pre-project site characterization as well as post-installation effects monitoring), stakeholder outreach, and mitigation, as well as qualitative experience of the permitting process. Data are organized in categories of technology type, permitted capacity, pre- and post-installation, geographic location, and funding types. We also compare our findings with earlier logic models created for the Department of Energy (i.e., Reference Models). Environmental studies most commonly performed were for Fish and Fisheries, Noise, Marine Habitat/Benthic Studies and Marine Mammals. Studies for tidal projects were more expensive than those performed for wave projects and the range of reported project costs tended to be wider than ranges predicted by logic models. For eight projects reporting full project costs, from project start to FERC or USACE permit, the average amount for environmental permitting compliance was 14.6%.

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    Energies
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    Authors: Sirko Bartholomay; Sascha Krumbein; Sebastian Perez‐Becker; Rodrigo Soto‐Valle; +3 Authors

    AbstractThis paper presents an experimental assessment of a blended fatigue‐extreme controller for load control employing trailing edge flaps on a lab‐scale wind turbine. The controller blends between a repetitive model predictive controller that targets fatigue loads and a dedicated extreme load controller, which consists of a simple on‐off load control strategy. The Fatigue controller uses the flapwise blade root bending moments of the three blades as input sensors. The Extreme controller additionally uses on‐blade angle of attack and velocity measurements as well as acceleration measurements to detect extreme events and to allow for a fast reaction. The experiments are conducted on the Berlin Research Turbine within the large wind tunnel of the TU Berlin. In order to reproduce test cases with deterministic extreme wind conditions that follow industry standards, the wind tunnel was redesigned. The analyzed test cases are extreme direction change, extreme coherent gust, extreme operating gust and extreme coherent gust with direction change. The test cases are analyzed by on‐blade angle of attack and velocity measurements. The load control performance of the Blended controller is compared to the pure fatigue oriented and the pure extreme load controller. The Blended controller achieves a maximum flapwise blade root bending moment reduction of 23%, which is comparable to the reduction achieved by the Extreme controller.

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    Wind Energy
    Article . 2022 . Peer-reviewed
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    https://dx.doi.org/10.14279/de...
    Article . 2022
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      Wind Energy
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      https://dx.doi.org/10.14279/de...
      Article . 2022
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      Wind Energy
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    Authors: Shaohua Guan; Xiaocun Guan; Baoqi Wu; Jingbin Shi;

    The influence of electromagnetic induction coil launcher (EICL) system parameters on the launch performance was analyzed, and a method for measuring the launch performance of an EICL system with a muzzle velocity and energy conversion efficiency was proposed. The EICL system mainly includes a pulse power supply and launcher. The parameters of the pulse power supply mainly include the discharge voltage and the capacitance value of the capacitor bank. The structural parameters of the launcher mainly include the bore size of the launcher, the air gap length between the armature and the drive coil, the length and width of the drive coil, and the trigger position of the armature. Change in single or multiple parameters in the launch system will influence the launch performance. The influence of single or multiple parameters on the launch performance was summarized, and the physical law as analyzed. The influence law of the EICL system parameters on the launch performance was obtained, which lays a theoretical foundation for the optimization design of EICL. Finally, experimental verification was carried out by a single-stage test platform.

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    Energies
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    Authors: Jia, Zhaolin; Wu, Han; Chen, Hao; Li, Wei; +5 Authors

    The tension legs are the essential parts of the tension legs platform-type (TLP-type) floating offshore wind turbine (FOWT) against the extra buoyancy of FOWT. Therefore, the TLP-type FOWT will face the risk of tension leg failure. However, there are seldom analyses on the hydrodynamic response and tension leg failure performance of FOWT with inclined tension legs. In this paper, a hydrodynamic model was established using three-dimensional hydrodynamic theory and applied in the motion response and tension analyses of FOWT with conventional and new tension leg arrangements on Moses. The influence of draft and tension leg arrangement on the performance of FOWT with inclined tension legs were studied. The optimum draft was the height of the column and lower tensions were obtained for the new tension leg arrangement. Moreover, the tension leg failure performance of FOWT with inclined tension legs was evaluated under different failure conditions. The results illustrated that the FOWT with the new tension leg arrangement can still operate safely after one tension leg fails.

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  • Authors: Byungsul Min; Matthias Muller; Bettina Wolpensinger; Gerd Fischer; +3 Authors

    This article investigates the impact of the back-surface-field (BSF) thickness variation within a local aluminum contact on the performance of passivated emitter and rear contact solar cells. A significant difference of BSF thickness between contact endings and the center of dash-shaped contacts is verified experimentally by a comprehensive statistical analysis using scanning electron microscopy. The impact of local BSF thickness differences on the cell performance is studied with 3-D technology computer-aided design (TCAD) device simulations. Several device parameters such as BSF thicknesses, the doping concentration in the BSF profile at rear contacts, or the metallized area fraction at the cell rear side are varied. Our simulation study shows that the open-circuit voltage is mainly affected by locally reduced BSF thicknesses, resulting in an efficiency loss up to 0.14%abs or 0.84%abs, respectively, if an area fraction of 1% or 20% within a local contact has reduced BSF thicknesses. This effect can be minimized either by reducing the metallized area fraction at the cell rear side or by increasing the doping concentration in the BSF profile at aluminum rear contacts. In addition, we demonstrate that the 3-D simulations can be approximated with 2-D simulations by applying a single doping profile with an average BSF thickness, calculated with the harmonic mean.

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    Authors: Tarek O. Abdul Fattah; Janet Jacobs; Vladimir P. Markevich; Nikolay V. Abrosimov; +3 Authors

    Before lower purity, lower cost silicon (Si) materials, such as compensated Si, can play a role in the terawatt-level (TW) capacity of photovoltaics, a better understanding of the fundamental properties of impurities in compensated Si is essential. In this work, high-resolution photoluminescence (PL) has been used to study the charge carrier radiative recombination through Donor-Acceptor pairs (DAPs) in phosphorus (P) and gallium (Ga) co-doped Si material grown for solar cell applications. The high spectral resolution of our PL system, 0.06 meV, enables us to overcome hitherto prior issues of overlapping spectral lines, giving access to extremely fine structures associated with DA pair (DAP) recombination. Our results confirm the presence of three broad bands and a discrete line structure related to DAP luminescence. The comparison of the discrete line structure due to DAPs recombination in the PL spectra with the theoretically predicted one allows the accurate determination of the Ga ionization energy. Temperature-dependent PL is then used to understand the thermally-induced changes in the DAP luminescence. In particular, we observe that the radiative recombination channel remains active for distant DAPs up to ∼40 K, unlike that for close-range DAPs for which the radiative channel is quenched after only slight increases in the temperature range 10–25 K. Furthermore, the analysis of the temperature dependent changes in the PL intensity of the broad DAP bands up to ∼200 K is used to derive the ionization energy of P donors in compensated Si material. In light of this important information, the significance of using high resolution PL to analyse spectral features in compensated Si is demonstrated.

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    Journal of Science: Advanced Materials and Devices
    Article . 2023 . Peer-reviewed
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      Journal of Science: Advanced Materials and Devices
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    Authors: Simona Breidokaite; Gediminas Stankunas;

    In fusion devices, such as European Demonstration Fusion Power Reactor (EU DEMO), primary neutrons can cause material activation due to the interaction between the source particles and the targeting material. Subsequently, the reactor’s inner components become activated. For safety and safe performance purposes, it is necessary to evaluate neutron-induced activities. Activities results from divertor reflector and liner plates are presented in this work. The purpose of liner shielding plates is to protect the vacuum vessel and magnet coils from neutrons. As for reflector plates, the function is to shield the cooling components under plasma-facing components from alpha particles, thermal effects, and impurities. Plates are made of Eurofer with a 3 mm layer of tungsten, while the water is used for cooling purposes. The calculations were performed using two EU DEMO MCNP (Monte Carlo N-Particles) models with different breeding blanket configurations: helium-cooled pebble bed (HCPB) and water-cooled lithium lead (WCLL). The TENDL–2017 nuclear data library has been used for activation reactions cross-sections and nuclear reactions. Activation calculations were performed using the FISPACT-II code at the end of irradiation for cooling times of 0 s–1000 years. Radionuclide analysis of divertor liner and reflector plates is also presented in this paper. The main radionuclides, with at least 1% contribution to the total value of activation characteristics, were identified for the previously mentioned cooling times.

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    Authors: Md. Shofiqul Islam;

    Thin-film organic solar cell (OSC) performances have been investigated in detail by improved analytical computation in this work. The generation of excitons inside OSC has been estimated by using the optical transfer matrix method (OTMM) to include the optical phenomena of the incident light. The dissociation of these excitons into free charge carriers has been investigated to find the most appropriate one. OSC performances have been evaluated by an improved analytical solution of electrical transport equations including (i) exciton generation obtained from OTMM, (ii) dissociation probability incorporating Gaussian distribution to account for the natural fact of the difference in photon-energy producing excitons, (iii) recombination of charge carriers, all together. OSC properties such as JSC, VOC, FF, PCE, Pmax, absorbance, and quantum efficiency have been investigated with the variation of different parameters; this might be useful to improve OSC. Again, the presented detailed derivations of analytical expressions would be helpful for clear understanding.

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    Authors: C Salazar Mejía; T Niehoff; M Straßheim; E Bykov; +3 Authors

    Abstract Magnetic refrigeration is a highly active field of research. The recent studies in materials and methods for hydrogen liquefaction and innovative techniques based on multicaloric materials have significantly expanded the scope of the field. For this reason, the proper characterization of materials is now more crucial than ever. This makes it necessary to determine the magnetocaloric and other physical properties under various stimuli such as magnetic fields and mechanical loads. In this work, we present an overview of the characterization techniques established at the Dresden High Magnetic Field Laboratory in recent years, which specializes in using pulsed magnetic fields. The short duration of magnetic-field pulses, lasting only some ten milliseconds, simplifies the process of ensuring adiabatic conditions for the determination of temperature changes, Δ T a d . The possibility to measure in the temperature range from 10 to 400 K allows us to study magnetocaloric materials for both room-temperature applications and gas liquefaction. With magnetic-field strengths of up to 50 T, almost every first-order material can be transformed completely. The high field-change rates allow us to observe dynamic effects of phase transitions driven by nucleation and growth as well. We discuss the experimental challenges and advantages of the investigation method using pulsed magnetic fields. We summarize examples for some of the most important material classes including Gd, Laves phases, La–Fe–Si, Mn–Fe–P–Si, Heusler alloys and Fe–Rh. Further, we present the recent developments in simultaneous measurements of temperature change, strain, and magnetization, and introduce a technique to characterize multicaloric materials under applied magnetic field and uniaxial load. We conclude by demonstrating how the use of pulsed fields opens the door to new magnetic-refrigeration principles based on multicalorics and the ‘exploiting-hysteresis’ approach.

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    JPhys Energy
    Article . 2023 . Peer-reviewed
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    JPhys Energy
    Article . 2023
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      JPhys Energy
      Article . 2023 . Peer-reviewed
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      JPhys Energy
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    Authors: Xiaonan Lu; Lu Deng; Sarah A. Saslow; Hongshen Liu; +7 Authors

    Vanadium-containing glasses have aroused interest in several fields such as electrodes for energy storage, semiconducting glasses, and nuclear waste disposal. The addition of V2O5, even in small amounts, can greatly alter the physical properties and chemical durability of glasses; however, the structural role of vanadium in these multicomponent glasses and the structural origins of these property changes are still poorly understood. We present a comprehensive study that integrates advanced characterizations and atomistic simulations to understand the composition-structure-property relationships of a series of vanadium-containing aluminoborosilicate glasses. UV-vis spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption near-edge structure (XANES) have been used to investigate the complex distribution of vanadium oxidation states as a function of composition in a series of six-component aluminoborosilicate glasses. High-energy X-ray diffraction and molecular dynamics simulations were performed to extract the detailed short- and medium-range atomistic structural information such as bond distance, coordination number, bond angle, and network connectivity, based on recently developed vanadium potential parameters. It was found that vanadium mainly exists in two oxidation states: V5+ and V4+, with the former being dominant (∼80% from XANES) in most compositions. V5+ ions were found to exist in 4-, 5-, and 6-fold coordination, while V4+ ions were mainly in 4-fold coordination. The percentage of 4-fold-coordinated boron and network connectivity initially increased with increasing V2O5 up to around 5 mol % but then decreased with higher V2O5 contents. The structural role of vanadium and the effect on glass structure and properties are discussed, providing insights into future studies of sophisticated structural descriptors to predict glass properties from composition and/or structure and aiding the formulation of borosilicate glasses for nuclear waste disposal and other applications.

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    The Journal of Physical Chemistry B
    Article . 2021 . Peer-reviewed
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    Authors: William J. Peplinski; Jesse Roberts; Geoff Klise; Sharon Kramer; +3 Authors

    Costs to permit Marine Energy projects are poorly understood. In this paper we examine environmental compliance and permitting costs for 19 projects in the U.S., covering the last 2 decades. Guided discussions were conducted with developers over a 3-year period to obtain historical and ongoing project cost data relative to environmental studies (e.g., baseline or pre-project site characterization as well as post-installation effects monitoring), stakeholder outreach, and mitigation, as well as qualitative experience of the permitting process. Data are organized in categories of technology type, permitted capacity, pre- and post-installation, geographic location, and funding types. We also compare our findings with earlier logic models created for the Department of Energy (i.e., Reference Models). Environmental studies most commonly performed were for Fish and Fisheries, Noise, Marine Habitat/Benthic Studies and Marine Mammals. Studies for tidal projects were more expensive than those performed for wave projects and the range of reported project costs tended to be wider than ranges predicted by logic models. For eight projects reporting full project costs, from project start to FERC or USACE permit, the average amount for environmental permitting compliance was 14.6%.

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    Energies
    Article . 2021 . Peer-reviewed
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    Energies
    Article . 2021
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      Energies
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      Energies
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