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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

The design and assessment of net-zero buildings commonly focus exclusively on the operational phase, ignoring the embodied environmental impacts over the building life cycle. An analysis is presented on the consequences of integrating embodied impacts into the assessment of the environmental advantageousness of net-zero concepts. Fundamental issues needing consideration in the design process - based on the evaluation of primary energy use and related greenhouse gas emissions - are examined by comparing three net-zero building design and assessment cases: (1) no embodied impacts included, net balance limited to the operation stage only; (2) embodied impacts included but evaluated separately from the operation stage; and (3) embodied impacts included with the operation stage in a life cycle approach. A review of recent developments in research, standardization activities and design practice and the presentation of a case study of a residential building in Norway highlight the critical importance of performance indicator definitions and system boundaries. A practical checklist is presented to guide the process of incorporating embodied impacts across the building life cycle phases in net-zero design. Its implications are considered on overall environmental impact assessment of buildings. Research and development challenges, as well as recommendations for designers and other stakeholders, are identified.

Thermoacoustic technology emerges as a sustainable and low-carbon method for energy conversion, leveraging environmentally friendly working mediums and independence from electricity. This study presents the development of a multimode heat-driven thermoacoustic system designed to utilize medium/low-grade heat sources for room-temperature cooling and heating. We constructed both a simulation model and an experimental prototype for a single-unit direct-coupled thermoacoustic system, exploring its performance in heating-only, cooling-only, and hybrid heating and cooling modes. Internal characteristic analysis including an examination of internal exergy loss and a distribution analysis of key parameters was first conducted in the hybrid cooling and heating mode. The results indicated a positive-focused traveling-wave-dominant acoustic field within the thermoacoustic core unit, enhancing energy conversion efficiency. The output system performance was subsequently tested under different working conditions in the heating-only and cooling-only modes. A maximum output heating power of 2.3 kW and a maximum COPh of 1.41 were observed in the heating-only mode. Meanwhile, a cooling power of 748 W and a COPc of 0.4 were obtained in the typical cooling condition at 7 °C when operating in cooling-only mode. These findings underscore the promising potential of thermoacoustic systems for efficiently utilizing medium/low-grade heat sources for cooling and/or heating applications in the future.

Abstract This study presents an evaluation of the error induced by neglecting the effect of air compressibility in modelling Oscillating Water Column (OWC) wave energy converters. A compressible two phases CFD model in the open-source software package OpenFOAM® is validated and then used to simulate a fixed OWC device, detached from the sea bottom. A comparative analysis of the results obtained by simulating the device at full-scale (1:1) and at four smaller scales (1:50, 1:25, 1:10 and 1:5) is performed in order to assess the scale effects associated with air compressibility. Indeed, for the air pressure levels considered in the simulations (up to 350 Pa at model scale 1:50), the effect of neglecting the air compressibility results in an overestimation up to about 15% for the air pressure in the OWC chamber and the subsequent air volume flux, but less than 10% for the capture width ratio. This overestimation increases with increasing pressure level. Results are analysed in terms of dimensionless parameters and a new parameter, strongly related to the compressible effects, is proposed and used to provide generalized equations delivering correction factors.

The use of bio-plastic-based packaging as an alternative to conventional plastic packaging is increasing. Among the plethora of different bio-based plastics, the most relevant ones are those that, at the end of their life, can be treated with the organic fraction of municipal solid waste. Even in these cases, their impact on the waste processing and recycling is not always positive. This study aim to assess on a laboratory scale the influence on combined anaerobic digestion and composting industrial processes of a bio-based plastic film, namely cellulose acetate (CA), in pure and modified (additions of additive) forms. CA films were mixed with organic waste and subjected to: (i) anaerobic digestion; (ii) active composting and (iii) two stages of curing composting. Anaerobic digestion and composting were monitored through methane yield and oxygen uptake respectively; additionally, the bio-plastics degree of disintegration was assessed during all the processes. The final disintegration of pure and modified CA was 73.82% and 54.66%, respectively. Anaerobic digestion contributes to the disintegration of the material, while aerobic treatment appears to be nearly ineffective, especially for modified CA. The presence of cellulose acetate during anaerobic digestion of food waste increased the methane yield by about 4.5%. Bioassay confirmed the absence of possible toxic effects on the final compost from the bio-plastic treatment. Although bio-based materials are not the only solution to plastic pollution, the findings confirm the need to upgrade the organic waste treatment plants and the necessity to revise the requirements for the use of compost in agriculture.

AbstractIn order to avoid autoreclosure onto a permanent fault, a new numerical algorithm for fault type determination is presented. It estimates the fault distance, as well, and can be utilized in the field of distance protection. The new approach, mathematical model and the solution for the earthless faults is given. For the purpose of unknown fault distance and arc voltage amplitude estimation, the Least Error Squares Method is used. The new algorithm is tested through numerous computer simulations and in the laboratory environment.

One-stage autotrophic nitrogen (N) removal, requiring the simultaneous activity of aerobic and anaerobic ammonium oxidizing bacteria (AOB and AnAOB), can be obtained in spatially redox-stratified biofilms. However, previous experience with Membrane-Aerated Biofilm Reactors (MABRs) has revealed a difficulty in reducing the abundance and activity of nitrite oxidizing bacteria (NOB), which drastically lowers process efficiency. Here we show how sequential aeration is an effective strategy to attain autotrophic N removal in MABRs: Two separate MABRs, which displayed limited or no N removal under continuous aeration, could remove more than 5.5 g N/m(2)/day (at loads up to 8 g N/m(2)/day) by controlled variation of sequential aeration regimes. Daily averaged ratios of the surficial loads of O(2) (oxygen) to NH(4)(+) (ammonium) (L(O(2))/L(NH(4))) were close to 1.73 at this optimum. Real-time quantitative PCR based on 16S rRNA gene confirmed that sequential aeration, even at elevated average O(2) loads, stimulated the abundance of AnAOB and AOB and prevented the increase in NOB. Nitrous oxide (N(2)O) emissions were 100-fold lower compared to other anaerobic ammonium oxidation (Anammox)-nitritation systems. Hence, by applying periodic aeration to MABRs, one-stage autotrophic N removal biofilm reactors can be easily obtained, displaying very competitive removal rates, and negligible N(2)O emissions.

In industrialized countries, large amounts of mineral wastes are produced. They are re-used in various ways, particularly in road and earth constructions, substituting primary resources such as gravel. However, they may also contain pollutants, such as heavy metals, which may be leached to the groundwater. The toxic impacts of these emissions are so far often neglected within Life Cycle Assessments (LCA) of products or waste treatment services and thus, potentially large environmental impacts are currently missed. This study aims at closing this gap by assessing the ecotoxic impacts of heavy metal leaching from industrial mineral wastes in road and earth constructions. The flows of metals such as Sb, As, Pb, Cd, Cr, Cu, Mo, Ni, V and Zn originating from three typical constructions to the environment are quantified, their fate in the environment is assessed and potential ecotoxic effects evaluated. For our reference country, Germany, the industrial wastes that are applied as Granular Secondary Construction Material (GSCM) carry more than 45,000 t of diverse heavy metals per year. Depending on the material quality and construction type applied, up to 150 t of heavy metals may leach to the environment within the first 100 years after construction. Heavy metal retardation in subsoil can potentially reduce the fate to groundwater by up to 100%. One major challenge of integrating leaching from constructions into macro-scale LCA frameworks is the high variability in micro-scale technical and geographical factors, such as material qualities, construction types and soil types. In our work, we consider a broad range of parameter values in the modeling of leaching and fate. This allows distinguishing between the impacts of various road constructions, as well as sites with different soil properties. The findings of this study promote the quantitative consideration of environmental impacts of long-term leaching in Life Cycle Assessment, complementing site-specific risk assessment, for the design of waste management strategies, particularly in the construction sector.